问题 选择题

下列表示对应化学反应的离子方程式正确的是                               (  )

A.向银氨溶液中滴加乙醛:

CH3CHO +2[Ag(NH3)2]+ + H2OCH3COO + NH4+ +3NH3 + 2Ag↓+2H+

B.苯酚钠溶液中通入少量CO2

C.硫酸氢铵溶液中滴加少量NaOH溶液:H++NH4++2OH=NH3·H2O+H2O

D.氯乙酸与足量的氢氧化钠溶液共热:CH2ClCOOH+OHCH2ClCOO+H2O

答案

答案:B

题目分析:A、乙醛发生银镜反应的离子方程式为CH3CHO +2[Ag(NH3)2]+ + 2OHCH3COO + NH4+ +3NH3 + 2Ag↓+H2O,A不正确;B、苯酚的酸性弱于碳酸但强于碳酸氢钠,因此苯酚钠溶液中通入少量CO2的离子方程式为,B正确;C、硫酸氢铵溶液中滴加少量NaOH溶液的离子方程式为H++OH=H2O,C不正确;D、卤代烃在氢氧化钠溶液中发生水解反应,则氯乙酸与足量的氢氧化钠溶液共热的离子方程式为CH2ClCOOH+2OHHOCH2COO+H2O+Cl,D不正确,答案选B。

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