问题 单项选择题

用雷氏铵盐溶液沉淀生物碱时,最佳条件是

A.碱性水溶液
B.酸性水溶液
C.中性水溶液
D.95%乙醇溶液
E.氯仿

答案

参考答案:B

解析: 本题考查生物碱分离中的沉淀法。
水溶性生物碱遇生物碱沉淀试剂可以从中草药的酸水提取液中沉淀析出,滤出沉淀,再用适当的时机进行分解,最后分出生物碱。最常采用的是雷氏铵盐(硫氰化铬银)沉淀法。具体操作时将烟酸水提取液滴加饱和的雷氏铵盐水溶液,使生物碱沉淀完全。过滤后将沉淀溶于丙酮,再在此溶液中加入饱和的硫酸银水溶液,使生物碱雷氏铵盐沉淀转变为溶于水的硫酸生物碱盐,而雷氏盐转变为银盐(硫氰化铬银)沉淀,过滤后除去。在滤液中加入计算两的氯化钡溶液,使过量的硫酸银转变成硫酸钡及氯化银沉淀,同时生物碱的硫酸盐也转变成盐酸盐,过滤去除沉淀,滤液中含有生物碱的盐酸盐,蒸干即可得到。

完形填空
Lang Lang is a world-class young pianist who grew up in Shenyang. He went to a piano school in Beijing when he was just eight, "You need fortune(运气)," his father said. "But     you work hard, no fortune will come."
What made him      was that his piano teacher in Beijing didn't like him. "You have no talent(天赋).You will never be a pianist." As an eight-year-old boy, Lang Lang was badly      . He decided that he didn't want to be a pianist any more. For the next two weeks, he didn't touch the piano. Wisely(明智的)his father didn't     ,but wait.
Luckily the day came when his teacher asked him to play some holiday songs. He didn't want to, but as he placed his fingers on the piano keys, he       he could show other people that he had ability to do it well. That day he told his father that he wanted to     with a new teacher. From that point on, everything turned around.
He started        competitions. In the 1994 International Young Pianists Competition when it was announced that Lang Lang had won, he was too       to hold back his tears. Soon it was clear that he couldn't stay in China forever-he had to play on the world's big stages. In 1997 Lang Lang      again, this time to Philadelphia, US. There he spent two years practicing and by 1999 he had worked hard enough for fortune to take over.After his     performance at Chicago's Raviniu Festival, gigs(演奏会)in Lincoln Center and Camegie Hall started pouring in. Lang Lang finally worked to reach the place where fortune spots(找到)him, and lets him shine.
小题1:
A.ifB.unlessC.whenD.since
小题2:
A.energeticB.happyC.luckyD.sad
小题3:
A.hurtB.illC.brokenD.scared
小题4:
A.hearB.pushC.eatD.sleep
小题5:
A.realizedB.explainedC.forgotD.noticed
小题6:
A.argurB.danceC.studyD.interview
小题7:
A.winningB.beatingC.watchingD.refusing
小题8:
A.annoyedB.madC.tiredD.excited
小题9:
A.startedB.leftC.movedD.performed
小题10:
A.helpfulB.meaningfulC.successfulD.useful
单项选择题