问题 填空题

某学生取9g淀粉溶于水,为测定淀粉的水解百分率,其程序如图:

(1)各步所加试剂为:A______、B______、C______、D______.

(2)只加A溶液而不加B溶液是否可以______,理由______.

(3)当析出2.16g沉淀时,淀粉水解率为______.

答案

(1)测定淀粉的水解完全与否,加NaOH中和H2SO4后,加银氨溶液或新制Cu(OH)2悬浊液,检验-CHO,所以淀粉水解,A为H2SO4作催化剂,加入的B为NaOH,中和掉H2SO4,因为氧化反应不能在酸性条件下发生,C为碘水,D为银氨溶液,银氨溶液和醛发生氧化还原反应生成银单质,

故答案为:H2SO4;NaOH;碘水;[Ag(NH32]OH;

(2)银镜反应必须在碱性条件下才能发生反应,在酸性条件下不发生反应,所以加入的氢氧化钠溶液将硫酸中和掉而使环境呈碱性;

故答案为:不可以;银镜反应必须在碱性条件下发生,所以必须加入NaOH溶液将催化剂H2SO4中和掉;

(3)(C6H10O5n淀粉+nH2O

催化剂
nC6H12O6(葡萄糖),

(C6H10O5)n~nC6H12O6~2nAg

162n 216ng

x2.16g

淀粉质量为:x═1.62g,

则淀粉的水解率为

1.62g
9g
×100%=18%;

故答案为:18%.

单项选择题 A1/A2型题
问答题

Passage Four

Despite their names, satin and soman are exceptionally ugly sisters. They are organophosphorous nerve gases. They are cheap and simple to manufacture. And mere milligrams—just a drop—of either is enough to kill an adult in a couple of minutes. They therefore make particularly fine weapons of mass destruction, equally popular with rogue dictators who have not been able to build nuclear bombs and with weird cults such as Aum Shinrikyo, which gassed the Tokyo subway in 1995.

Detecting them soon enough to prevent their effects can be difficult. Even detecting them after the event—if you are, for example, a United Nations weapon inspector—can be haphazard. But help may be at hand. A paper in this month’s edition of Analytical Chemistry, by George Murray and his team at John Hopkins University’s Applied Physics Laboratory in Laurel, Maryland, reports a new way of picking up minute qualities of the two gases without the risk of false alarms from legitimate organophosphorous compounds such as insecticides.

Dr Murray’s detector consists of a fiber-optic cable that has one end plugged into a laser and the other coated with a metal called europium. The laser generates blue light, and europium has the property of shining red when exposed to blue light of the correct wavelength—an effect that is exploited in many optical devices. But the metal possesses a second property that makes it uniquely suitable for Dr. Murray’s purpose: it reacts ply with organophosphates, and when it does so, the wavelength of the light that is emitting changes perceptibly.

To stop his detector going off in response to the wrong signals such as insecticide on the flea collar of a dog, Dr Murray has resorted to a second trick. The europium is embedded in a plastic film that binds specifically to sarin or soman (they are very similar molecules), using special pockets called molecular imprints that have been chemically etched into it. The organophosphates commonly used as pesticides do not fit into these pockets; and so fail to react with the metal. The result is a detector that is both sensitive ( it can pick up concentrations of as seven nerve-gas molecules in a trillion) and reasonable fast (it is able to sound the alarm within 30 seconds).

So far, Dr Murray has tested his device only on soman dissolved in water. This is mainly a safety measure, because water-borne nerve agents are easier to handle than those in gaseous form. But soman or sarin-contaminated water supplies are a real hazard in themselves—and not just in far-flung war zones. In America, for example, there are occasional leaks from military bases. The most recent was from Tooele Chemical Disposal Facility in Utah, one of the sites where the country’s chemical weapons stockpile is being destroyed. At the moment it would be hard to work out if any material from such a spill had found its way into the water supply until people started to become ill.

Dr Murray seems confident, however, that his technology will work just as well on sarin and saman gas, and has prepared "smart" cards coated with the mixture of europium and plastic to detect airborne nerve gases. Unfortunately, he does not, at the moment, have access to any place where the safety regulations will permit him to try them out. But if UN inspectors were ever allowed back into Iraq, he might have a chance.

What is a special property of this device ?()