问题 填空题

正极材料为LiCoO2的锂离子电池已被广泛用作便携式电源。但钴的资源匮乏限制了其进一步发展。

(1)橄榄石型LiFePO4是一种潜在的锂离子电池正极材料,它可以通过(NH4)2Fe(SO4)2、H3PO4与LiOH溶液发生共沉淀反应,所得沉淀经80℃真空干燥、高温成型而制得

①共沉淀反应投料时,不将(NH4)2Fe(SO4)2和LiOH溶液直接混合的原因是________________

②共沉淀反应的化学方程式为____。

③高温成型前,常向LiFePO4中加入少量活性炭黑,其作用除了可以改善成型后LiFePO4的导电性能外,还能________。

 (2)废旧锂离子电池的正极材料试样(主要含有LiCoO2及少量Al、Fe等)可通过下列实验方法回收钴、锂。

①在上述溶解过程中,S2O32-被氧化成SO42-,LiCoO2在溶解过程中反应的化学方程式为____。

②Co(OH)2在空气中加热时,同体残留率随温度的变化如下图所示。已知钴的氢氧化物加热至290℃时已完全脱水,则1000℃时,剩余固体的成分为______(填化学式);在350~ 400℃ 范围内,剩余固体的成分为_________(填化学式)。

答案

(1)①Fe2+在碱性条件下更易被氧化(凡合理答案均可);②( NH4)2Fe(SO4)2+ LiOH十H3PO4=LiFePO4↓十 2NH4HSO4+H2O ;③与空气中O2反应,防止LiFePO4中的Fe2+被氧化(凡合理答案均可)

(2) ①8LiCoO2十Na2S2O3+11H2SO4=4Li2SO4+ 8CoSO4 +Na2SO4 +11H2O ;②CoO;Co2O3、Co3O4

阅读理解

Some people in Manchester, Britain, will soon be paying for goods and services with so-called “smart” credit cards. These cards are more secure than the traditional magnetic-strip version and can be used to travel on buses, check bank accounts and do shopping.

The Manchester project is one of the biggest smart card schemes in the world. Every time people use the cards on a bus or train, the fare is deducted (reduced) from the value of the card. When they have no credit left, the cards can be recharged at a local shop.

A smart card looks just like a normal plastic card but it has a silicon chip in it. It is possible for the same silicon chip to perform a number of different functions, so one plastic card in your pocket could do a large number of different jobs. The card has much more memory space than a magnetic-strip card, so many more things can be recorded on it.There are two types of smart cards. One is the contact card which is used in the same way as a magnetic-strip card.

Information is transferred by running the card through a narrow opening in an electronic reader. In the slot, electronic probes make contact with the magnetic-strip or silicon ship and read the information. The other type is the contactless smart card where the electronic reader communicates with the card by short-range radio waves. This makes the card quicker and more convenient to use because it does not have to leave your wallet.  It is also more reliable as it is not easily influenced by scratches or dirt. However, the biggest advantage that smart cards have over magnetic-strip cards is that they are more secure. They are much more difficult to make than conventional cards and they have to be made by specially trained manufacturers. In addition, they have a large number of extra security features on them and if a smart card gets lost or stolen a quick phone-call to the distributor ensures that its individual number is made invalid and unreadable. This can be done more quickly than with a magnetic-strip card.

小题1:A smart credit card can do many kinds of jobs because ____ .

A.it is smart

B.it is a plastic card

C.it has a silicon chip in it

D.it can be recharged小题2:“ The cards can be recharged” means that ____ .

A.the card can be put into a new charge of electricity

B.the cards can be changed into new ones

C.the cards can be put to use again

D.the cards can be recycled小题3:What are the advantages of smart credit cards over traditional ones?

A.they can store more information

B.they are more secure

C.they are more convenient to use

D.all of the above小题4:Which of the following statements is TRUE according to the passage?

A.Contactless cards are more convenient to use than contact ones

B.Smart cards are more expensive to manufacturer

C.By means of long-range radio waves contactless cards can communicate with the electronic reader

D.A smart credit card and a normal plastic card are the same thing

解答题