将足量铁投入到200mLH2SO4和CuSO4的混和溶液中,充分反应后,产生H21.12L(标准状况),铁块的质量减轻了1.2g.求原溶液中c(H2SO4)及c(CuSO4).(假设反应前后溶液的体积不变)
Fe+H2SO4=FeSO4 +H2↑
56g 1mol 22.4L
m1(Fe) n(H2SO4) 1.12L
m1(Fe)=
=2.8g 56g×1.12L 22.4L
n(H2SO4)=
=0.05mol 1mol×1.12L 2.24L
V(液)=V(H2SO4)=V(CuSO4)=200mL=0.2L
c(H2SO4)=
=n(H2SO4) V(H2SO4)
=0.25mol/L0.05mol 0.2L
Fe+CuSO4=FeSO4+Cu
56g 1mol 64g
m2(Fe) n(CuSO4) m(Cu)
m(Cu)=
×m2(Fe)=64g 56g
m2(Fe) 8 7
由题意得:m1(Fe)+m2(Fe)-m(Cu)=1.2g
2.8g+m2(Fe)-
m2(Fe)=1.2g8 7
m2(Fe)=11.2g
n(CuSO4)=
=1mol×m2(Fe) 56g
=0.2mol 1mol×11.2g 56g
c(CuSO4)=
=n(CuSO4) V(CuSO4)
=1mol/L 0.2mol 0.2L
答:原溶液中c(H2SO4)=0.25mol/L,c(CuSO4)=1mol/L.