问题 填空题

将铁与氧化铁的锟合物15g,加入150mL稀H2SO4中,标准状况下放出H2 1.68L,同时铁和氧化铁均无剩余,向溶液中滴入KSCN溶液,未见颜色变化.

(1)写出所有发生的反应方程式:______

(2)混合物中铁的质量是______克.

(3)为了中和过量的H2SO4,且使Fe2+完全转化成Fe(OH)2,共耗费3mol/L的氢氧化钠溶液200mL,则原硫酸的物质的量浓度为______.

答案

(1)因铁、氧化铁都能与盐酸反应:Fe+H2SO4=FeSO4+H2↑ Fe2O3+3H2SO4=Fe2(SO43+3H2O,又因反应后溶液中无Fe3+,所以有反应:Fe+Fe2(SO43=3FeSO4

故答案为:Fe+H2SO4=FeSO4+H2↑、Fe2O3+3H2SO4=Fe2(SO43+3H2O、Fe+Fe2(SO43=3FeSO4

(2)从Fe+H2SO4=FeSO4+H2 ↑方程式可以算出和硫酸生成1.68LH2的铁为0.075mol,其质量为4.2g,剩下15-4.2=10.8g混合物发生如下反应:

     Fe2O3+3H2SO4=Fe2(SO4)3+3H2O  Fe2(SO4)3+Fe=3FeSO4

      n              n              n       n

  所以剩余混合物中Fe2O3和Fe的物质的量应该为1:1,可以算出各为0.05mol,则m(Fe2O3)=8g,m(Fe)=4.2+2.8=7g,故答案为:7;

(3)因为反应后溶液中无fe3+存在,且固体没有剩余,则全都是以Fe2+的形式存在

    H2SO4 ~2NaOH

    0.3mol    3mol/L*0.2L

 原硫酸的物质的量为0.3mol,

所以原稀H2SO4的物质的量浓度为0.3/0.15=2mol/L,故答案为:2mol/L.

单项选择题
改错题

单句改错。
1. We are thinking to make the computer "think" like a man.                                              
                   A            B                               C          D                                                
2. The little girl practices playing violin every day.                         
                                A            B         C      D                                                             
3. It's important of us to protect our environment.                           
     A                  B  C         D                                                                                      
4. We're tired now. What about have a rest, sir?                              
        A      B                     C             D                                                                        
5. A group of us is going to help the elderly do some cleaning.                
               A        B                                   C        D                                                       
6. The teacher asked us to write a 8-hundred-word composition in class.                   
                                         A     B          C                                         D                        
7. My work keeps me busily all day.                                                                            
             A      B              C       D                                                                                 
8. The 2008 Olympic Games will be taken place in Beijing
                 A                             B        C                    D                                                
9. Sandy was riding his bike while she fell off and hurt herself.
                     A                         B               C              D                                               
10. Australia is also an English-spoken country, just like England and America.                       
                         A                  B                                    C                  D                         
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