问题 计算题

(正常进度)

(1)写出以30%KOH溶液为电解质溶液,甲烷燃料电池的负极电极反应式______。

(2)在标准状况下,甲烷和氧气的混合气体224mL,充分燃烧后,将生成的气体通入100mL 0.02mol/L的石灰水,得到0.1g白色沉淀。求混合气体中甲烷和氧气的体积比。

答案

(1)CH4-8e+10OH=CO32+7H2O (3分)(2)①如果氢氧化钙过量,甲烷与氧气的体积比为1:9;②如果CO2过量,烷与氧气的体积比为3:7

(1)在原电池中负极失去电子,发生氧化反应。所以甲烷在负极通入。由于电解质是氢氧化钾,所以负极反应式为CH4-8e+10OH=CO32+7H2O。

(2)考查根据方程式进行的有关计算。

有关反应的化学方程式为:CH4+2O2=CO2+2H2O、CO2+Ca(OH)2=CaCO3↓+H2O、

CaCO3+CO2+H2O====Ca(HCO3)2

混合气是0.224L÷22.4L/mol=0.01mol,氢氧化钙是0.02mol/L×0.1L=0.002mol,生成的碳酸钙是0.1g÷100g/mol=0.001mol。则

①如果氢氧化钙过量,则反应中生成的CO2就是0.001mol,则氧气就是0.009mol,所以甲烷与氧气的体积比为1:9

②如果CO2过量,生成碳酸钙沉淀又被剩余的CO2反应生成碳酸氢钙。则生成的CO2为0.03mol,则氧气就是0.007mol,所以甲烷与氧气的体积比为3:7

单项选择题 A1/A2型题
阅读理解

Animals can move from place to place, but plants cannot. When an animal is under attack, it can run away or fight back.. Plants certainly cannot run away, and they lack teeth and claws. But plants can defend themselves by using both physical and chemical means.

Some plants have their own ways to keep animals away. For example, the leaves of the holly plant have sharp spines (刺) that discourage grass-eating animals. Holly leaves on lower branches have more spines than leaves on upper branches. This is because the lower leaves are easier for most animals to reach.

Some plants, such as the oak tree, have thick and hard leaves that are difficult for animals to eat. Some grasses may contain a sandy material; eating such grasses wears down the animal's teeth.

Many plants also have chemical defenses. Some plants produce chemicals that taste bitter or cause an unpleasant reaction. Some plants may fight against an attack by increasing the production of these chemicals. When a caterpillar (毛虫) bites a tobacco leaf, the leaf produces a chemical messenger. This messenger sends to the roots the information to produce more nicotine. The higher levels of nicotine discourage the caterpillar.

Many plants depend on both physical and chemical defenses. A certain plant in China, for

instance, has prickly (多刺的) leaves, and each prickle contains poisonous venom (毒液) A single experience with this kind of plant will teach an animal to stay away from it in the future.

小题1:The holly plant has more spines on the lower leaves because most animals________.

A.are not tall enough

B.like the lower leaves only

C.are not clever enough

D.can get the lower leaves easily小题2:To defend themselves, oak trees use________.

A.chemical means

B.physical means

C.bitter chemicals

D.sandy materials小题3:How does tobacco protect itself against an attack from a caterpillar?

A.Its leaves fight against the attack by physical means.

B.Its roots send a messenger to discourage the caterpillar.

C.Its roots increase the production of nicotine when it is attacked.

D.Its leaves produce poisonous sand to drive the caterpillar away.小题4:What would be the best title for this passage?

A.Plants and Animals

B.How Plants Defend Themselves

C.Attacks and Defenses

D.How Animals Eat Plant Leaves