问题 填空题

氢氧燃料电池是符合绿色化学理念的新型发电装置。如图为电池示意图,该电池电

极表面镀一层细小的铂粉,吸附气体的能力强,性质稳定,请回答:

(1)      氢氧燃料电池的能量转化形式主要是____               __,

(2)      在导线中电子流动方向为 ____ →   __(用a、b表示)。

(3) 负极反应式为__________                  ________。

(4) 电极表面镀铂粉的原因为_____                    ____。

答案

(1)由化学能转化为电能       (2)由a到b

(3)2H2 + 4OH--4e- = 4H2O 或 H2+2OH--2e- = 2H2O

(4)增大电极单位面积吸附H2、O2分子数,加快电极反应速率

题目分析:(1)根据原电池的工作原理可知,氢氧燃料电池的能量转化形式主要是由化学能转化为电能。

(2)原电池中较活泼的金属是负极,失去电子,发生氧化反应。电子经导线传递到正极,所以溶液中的阳离子向正极移动,正极得到电子,发生还原反应,所以氢气在负极通入,失去电子。氧气在正极通入,得到电子,则在导线中电子流动方向为由a到b。

(3)负极氢气失去电子,且电解质溶液显碱性,则负极电极反应式为H2+2OH--2e- = 2H2O。

(4)电极表面镀铂粉后增大电极单位面积吸附H2、O2分子数,加快电极反应速率。

点评:该题是高考中的常见题型,属于中等难度的试题。试题基础性强,侧重对学生能力的培养和解题方法的指导与训练,有助于培养学生的逻辑推理能力和规范的答题能力。该题的关键是明确原电池的工作原理,然后结合题意灵活运用即可。

单项选择题

It’s obvious that humans are fundamentally different from other animal species. It’s not so easy, though, to identify the traits that make human beings so special. Scientists realized long ago that other animals make tools, play jokes and even have a sense of justice and altruism—all things we once thought were unique to our species.

Now a paper in the journal Current Biology has added another behavior to the list of what other animals share with us—and this one isn’t quite so charming. After years of field observations in Uganda’s Kibale National Park, John Mitani of the University of Michigan and several colleagues have concluded that chimps wage war to conquer new territory.

"We already knew that chimps kill each other," says Mitani. "We’ve known this for a long time." What scientists didn’t know for certain, at least in cases in which groups of chimps banded together to kill others, was why. One hypothesis, advanced more than a decade ago by anthropologist Richard Wrangham, was the idea of territorial conquest; circumstantial evidence from both Gombe and Mahale national parks in Tanzania bolstered the theory.

In Mahale, for example, male members of one group mysteriously vanished, and another group then expanded into what had been their land. In Gombe, an existing group dissolved into civil war, resulting in killings and land takeovers.

What’s especially chilling about the observation is that the murder rate appears to be so high. The anthropologists couldn’t be certain of how big a band the victims belonged to because they weren’t used to a human presence and thus couldn’t be accurately counted. But even a conservative estimate suggests that the death rate is significantly higher than you would see in war between human hunter-gatherer groups.

Mitani isn’t oblivious to the lesson some people might draw from the study. "Invariably, some will take this as evidence that the roots of aggression run very deep," he says, and therefore conclude that war is our evolutionary destiny. "Even if that were true," says Mitani, "we operate by a moral code that chimps don’t have."

Apart from that, he points out, the Pan troglodytes chimps he studies are one of two subspecies. The other is called Pan paniscus, also known as bonobos, and, says Mitani, "the latter, as far as we know, aren’t nearly as aggressive with respect to intergroup relations. Yet they’re equally close to us." That means that if we’re wired for warfare, we’re wired for peace too. Ultimately, the route we choose is still up to us.

The word "bolstered" (Line 5, Paragraph 3) has the closest meaning to()

A.held

B. challenged

C. proposed

D. confirmed

选择题