问题 问答题 简答题

高分子构型的异构有几种?各有什么特点?

答案

参考答案:高分子构型的异构有旋光异构和几何异构

(1)旋光异构:高分子全同立构(或等规立构):当取代基全部处于主链平面的一侧或者说高分子全部由一种旋光异构单元键接而成。间同立构(或间规立构):取代基相间的分布于主链平面的二侧或者说两种旋光异构单元交替键接。无规立构:当取代基在平面两侧作不规则分布或者说两种旋光异构体单元完全无规键接时。全同立构和间同立构高分子链易于结晶,而无规立构高分子链不易结晶。

(2)几何异构:1,4加聚的双烯类聚合物中,由于主链双键的碳原子上的取代基不能绕双键旋转,当组成双键的两个碳原子同时被两个不同的原子或基团取代时,即可形成顺反两种构型,它们称作几何异构体。顺式结构分子链与分子链之间的距离较大,不易结晶。反式结构分子链的结构比较规整,容易结晶。

选择题
阅读理解

A study published Monday found that people who sleep less tend to be fat, and experts said it’s time to find out if more sleep will fight fatness.

“We’ve put so much emphasis on diet and exercise that we've failed to recognize the value of good sleep,” said Fred Turek, a physician at Northwestern University.

Monday’s study from Eastern Virginia Medical School in Norfolk covered 1,000 people and found that total sleep time decreased as body mass index - a measure of weight based on height - increased.

Men slept an average of 27 minutes less than women and overweight and fat patients slept less than patients with normal weights, it said. In general the fatter subjects slept about 1.8 hours a week less than those with normal weights.

“Americans experience insufficient sleep and fat bodies. Clinicians are aware of the burden of fatness on patients,” the study said.

“Our findings suggest that major extensions of sleep time may not be necessary, as an extra 20 minutes of sleep per night seems to be associated with a lower body mass index,” it added.

“We caution that this study does not establish a cause-and-effect relationship between restricted sleep and fatness (but) investigations indicating success in weight loss via extensions of sleep would help greatly to set up such a relationship.”

The study was published in the Archives of Internal Medicine along with an editorial by Turek and Northwestern colleague Joseph Bass commenting on it and related research.

In an interview, Turek said some studies have shown sleep causes declines in an appetite suppressing protein hormone, and increases in another hormone that causes a longing for food. In addition neuropathies(神经疗法)in the brain governing sleep and fatness appear to overlap(重叠), he said.

Patness has been rising dramatically in developed countries and reached epidemic(流行病) levels in the United States, it added, leading to a variety of health problems.

66. What’s the passage mainly about?

A. People who sleep less tend to get fat.

B. Fat people need lots of sleep to lose weight.

C. Sleeping has nothing to do with fatness.

D. Fatness has been rising dramatically in developed countries.

67. According to the passage, which of the following is TRUE?

A. Lack of sleep causes declines in a desire limiting protein hormone.

B. Americans experience sufficient sleep and fat bodies.

C. The findings suggest that major extensions of sleep time may be necessary.

D. Fatness has been rising dramatically in America.

68. Which of the following is NOT close to the underlined word suppress?

A. limit          B. restrict       C. accept         D. control

69. According to the passage, which of the following people is the lowest possible one to get fatness?

A. Americans      B. Chinese        C. Japanese       D. English

70. We can conclude the attitude of the author is           according to the passage.

A. worried        B. uninterested   C. critical       D. optimistic