（17分）CO和H₂的混合气体俗称合成气，是一种重要的工业原料气，可以在一定条件下制备甲醇，二甲醚等多种有机物。工业上利用天然气（主要成分为CH₄）与水进行高温重整制备合成气。

（1） 已知：CH₄、H₂和CO的燃烧热分别为890.3kJ/mol、285.8kJ/mol和283.0kJ/mol，且1mol液态水汽化时的能量变化为44.0kJ。写出甲烷与水蒸气在高温下反应制取合成气的热化学方程式                  。

（2）在一定条件下，向体积为2L的密闭容器中充入0.40mol CH₄和0.60mol H₂O(g)，测得CH₄(g)和H₂(g)的物质的量浓度随时间变化如下表所示：

时间/min 物质 浓度	0	1	2	3	4
CH4	0.2mol·L—1	0.13 mol·L—1	0.1 mol·L—1	0.1 mol·L—1	0.09 mol·L—1
H2	0 mol·L—1	0.2 mol·L—1	0.3 mol·L—1	0.3 mol·L—1	0.33 mol·L—1

②3min时改变的反应条件是____________________（只填一种条件的改变）

（3）已知温度、压强、投料比X〔n(CH₄)/n(H₂O)〕对该反应的影响如图所示。

①图1中的两条曲线所示投料比的关系X₁____X₂(填“=”“>”或“<”下同)

②图2中两条曲线所示的压强比的关系：p₁_______p₂

（4）以天然气（设杂质不参与反应）、KOH溶液为原料可设计成燃料电池

①放电时，正极的电极反应式_______________________________________

②设装置中盛有100.0mL 3.0mol/L KOH溶液，放电时参与反应的氧气在标准状况下的体积为8.96L，放电过程中没有气体逸出，则放电完毕后，所得溶液中各离子浓度由大到小的关系为                     ____。

The nobler and more perfect a thing is, the later and slower it is becoming mature. A man reaches the mature (1) of his reasoning powers and mental faculties (2) before the age of twenty-eight; a woman at eighteen. And then, too, in the case of woman, it is the only reason of a sort--very mean in its (3) . That is why women remain children their whole life long; never seeing (4) but what is quite close to them, (5) fast to the present moment, taking appearance for (6) , and preferring (7) to matters of the first importance. For it is (8) his reasoning faculty that man does not live in the present only, (9) the brute, but looks about him and considers the past and the future; and this is the origin of (10) , as well as that of care and anxiety which so many people (11) Both the advantages and the disadvantages, which this (12) , are (13) in by the woman to a smaller extent because of her weaker power of reasoning. She may, in fact, be described as intellectually shortsighted, (14) , while she has an immediate understanding of what lies quite close to her, her field of (15) is narrow and does not reach to what is (16) ; so that things which are absent, or past, or to come, have much less effect upon women than upon men. This is the reason why women are inclined to be (17) and sometimes carry their desire to a (18) that borders upon madness. In their hearts, women think it is men’s business to earn money and theirs to spend it--if possible during their husband’s life, (19) , at any rate, after his death. The very fact that their husband hands them (20) his earnings for purposes of housekeeping strengthens them in this belief.

14（）

A.before

B.because

C.unless

D.until