问题 单项选择题

运输巷道管路吊挂不低于()

A.1.6m

B.1.8m

C.2m

答案

参考答案:B

填空题

(13分)Ⅰ.一氧化碳是一种用途相当广泛的化工基础原料。

(1)利用下列反应可以将粗镍转化为纯度达99.9%的高纯镍。

Ni(s)+4CO(g)Ni(CO)4(g) 该反应的ΔH  ▲ 0 (选填“>”或“=”或“<”)。

(2)在高温下一氧化碳可将二氧化硫还原为单质硫。已知:

C(s)+O2(g)=CO2(g)          ΔH1=-393.5 kJ·mol1

CO2(g)+C(s)=2CO(g)       ΔH2=+ 172.5 kJ·mol1

S(s)+O2(g)=SO2(g)         ΔH3=-296.0 kJ·mol1

请写出CO除SO2的热化学方程式                                 

(3)下图中左图是一碳酸盐燃料电池,它以CO为燃料,一定比例Li2CO3和Na2CO3低熔混合物为电解质,右图是粗铜精炼的装置图,现用燃料电池为电源进行粗铜的精炼实验。回答下列问题:

①写出A极发生的电极反应式                              

②要用燃料电池为电源进行粗铜的精炼实验,则B极应该与 极(填:“C”或“D”)相连。

③当消耗2.24 L(标况下)CO时,粗铜电极理论上减少铜的质量               ▲    (填:“大于”、“等于” 或“小于”)6.4克。

Ⅱ.(1)已知Na2CrO4溶液酸化时发生的反应为:2CrO42+2HCr2O72+H2O,若1L酸化后所得溶液中铬元素的总物质的量为0.55 mol,CrO42有10/11转化为Cr2O72。又知:常温时该反应的平衡常数K=1014。上述酸化后所得溶液的pH=    

(2)根据有关国家标准,含CrO42的废水要经化学处理,使其浓度降至5.0×107 mol·L1以下才能排放。含CrO42的废水处理通常有以下两种方法。

①沉淀法:加入可溶性钡盐生成BaCrO4沉淀[Ksp(BaCrO4)=1.2×1010],再加入可溶性硫酸盐处理多余的Ba2。加入可溶性钡盐后的废水中Ba2的浓度应不小于          mol·L1,然后再进行后续处理方能达到国家排放标准。

②还原法:CrO42Cr3Cr(OH)3。用该方法处理10 m3 CrO42的物质的量浓度为1.0×10—3 mol·L1的废水,至少需要绿矾(FeSO4·7H2O,相对分子质量为278)  Kg(保留两位小数)。

阅读理解
Professor Martin’s report says that children who attend a number of different schools,because their parents have to move around the country,probably make slow progress in their studies. There are also signs,says Professor Martin,that an unusually large number of such children are mentally affected.
The professor says,“It’s true,my personal feeling is that children should stay in one school. But our findings are based on research and not on any personal feelings. ”
Captain Thomas James,an Army lecturer for the past 20 years and himself a father of two,said,“I’ve never heard of such rubbish. Taking me for example. no harm is done to the education of my children,who change schools regularly—if they keep to the same system,as in our Army schools. In my experience—and I’ve known quite a few of them—Army children are as well adjusted as any others,if not more so. What the professor doesn’t appear to appreciate is the fact that in such situation children will adapt much better than grown-ups.”
When this reached Professor Martin,he said that at no time had his team suggested that all children were backward or mentally affected in some way,but simply that in their experience there was a clear tendency.
“Our findings show that while the very bright children can deal with regular changes without harming his or her general progress in studies,the majority of children suffer from constantly having to enter a new learning situation.”
小题1:Professor’s Martin’s report suggests that      
A.it may not be good for children to change schools too often
B.parents should not move around the country
C.changing schools is the reason of children making slow progress
D.more and more children are mentally affected
小题2: According to the passage,Professor Martin's personal feeling.
A.is the opposite of what his report has shown
B.is in a way supported by his research
C.has played a big part in his research
D.is based on the experience of his own children
小题3:From the passage,we can conclude that Captain James’ children_____.
A.have been affected by changing schools
B.go to ordinary state schools
C.can get used to the Army school education
D.discuss their education regularly with their father
小题4:About children and grown-ups,Captain James says that children____.
A.are generally poorly-adjusted
B.are usually less experienced
C.can adapt much more easily
D.can deal with changes quickly