问题 填空题

北京奥运会“祥云”火炬的燃料是丙烷(C3H8),亚特兰大奥运会火炬的燃料是丙烯(C3H6)。 (1)丙烷脱氢可得丙烯。

已知:C3H8(g)―→CH4(g)+HC≡CH(g)+H2(g)  ΔH1=156.6 kJ/mol

CH3CH=CH2(g)―→CH4(g)+HC≡CH(g) ΔH2=32.4 kJ/mol

则相同条件下,反应C3H8(g)―→CH3CH=CH2(g)+H2(g)的ΔH=________kJ/mol。

(2)以丙烷为燃料制作新型燃料电池,电池的正极通入O2和CO2,负极通入丙烷,电解质是熔融碳酸盐。电池反应方程式为_____________;放电时,CO32-移向电池的________(填“正”或“负”)极。

(3)碳氢化合物完全燃烧生成CO2和H2O。常温常压下,空气中的CO2溶于水,达到平衡时,溶液的pH=5.60,c(H2CO3)=1.5×10-5 mol/L。若忽略水的电离及H2CO3的第二级电离,则H2CO3HCO3+H+ 的平衡常数K1=________。(已知:10-5.60=2.5×10-6)

(4)常温下,溶液中c(H2CO3)________c(CO32-)(填“>”“=”或“<”),原因是___________________________(用离子方程式和必要的文字说明)。

答案

(1)124.2

(2)C3H8+5O2===3CO2+4H2O ;负

(3)4.2×10-7 mol/L

(4)> ;HCO3+H2OCO32-+H3O(或HCO3CO32-+H),HCO3+H2OH2CO3

单项选择题
单项选择题

Government officials reported three new cases of mad cow, bringing the total so far this year to 99. Last year, France recorded just 31 cases of the mad cow disease. The rising numbers are in part (1) a new testing program that focuses on cows that are most (2) . That program has (3) 39 cases. But still 60 new cases were identified in the usual way, (4) were found in 1999. Many scientists (5) that this year, five years after safety precautions were (6) , the number of cases would be (7) .

The rise in cases has (8) some scientists to question whether the disease can be transmitted in ways not yet understood. Scientists are still (9) the disease, first recognized in cows in 1986.

It appears that it is not caused by a bacteria, virus or fungus, but (10) infectious particles called prion, perhaps (11) a virus or other agent. The disease kills cells in the brain, (12) it spongy and full of holes.

France has taken more steps to (13) safety than most European countries, (14) refusing to take English beef (15) the European Union. But some scientists believe that France has not been (16) in imposing the ban on feed that (17) animal pans.

Some French officials hope that the sudden interest in mad cow disease will mean that French consumers will become educated about it, thereby recognizing that French beef is actually (18) controlled. Every cow is given a passport at birth, and extensive information about its parentage and (19) it was raised must be (20) to any slaughterhouse. When a diseased animal is found, the entire herd is destroyed.

19()

A.where

B.how

C.when

D.why