问题 填空题

(14分)元素及其化合物在生产、生活中具有广泛的用途。

Ⅰ.铬化学丰富多彩:

⑴在常温下,铬能缓慢与稀硫酸反应,生成蓝色溶液。与铜相比,其金属活泼性              。(填“强”或“弱”)

⑵Cr( OH)3和Al( OH)3类似,也是两性氢氧化物,在水中存在酸式和碱式电离平衡,其酸式电离方程式是                          

(3)工业上净化处理铬污染方法之一:将含K2Cr2O7酸性废水放入电解槽内,加入适量的NaCl,以Fe和石墨为电极进行电解。一段时间后,生成Cr(OH)3和Fe(OH)3沉淀除去(已知Ksp[ Fe(OH)3]=4.0×10-38,Ksp[Cr(OH)3]=6.0×l0-31)。已知电解后的溶液中c( Fe3+)为2.0×10-13mol/L,则溶液中c(Cr3+)为       mol/L。

Ⅱ.物质A~H有如图所示转化关系(部分生成物未列出)。A、E、F、G均为气体,D为贵重金属之一。

请回答下列问题:

(1)A分子是        分子(填“极性”或“非极性”),C溶液中的阳离子是      (写化学式,不考虑水的电离)。

(2)反应①的化学方程式为         ;反应③的离子方程式为             

答案

Ⅰ.(1)强;(2)Cr( OH)3H+ + CrO2+ H2O;(3)3.0×10-6

Ⅱ.(1)极性;[Ag(NH3)2]+

(2)4NH3+5O2 4NO+6H2O;

3Ag + 4H+ + NO3= 3Ag+ + NO↑+ 2H2O

题目分析:Ⅰ(1)在常温下,铬能缓慢与稀硫酸反应,生成蓝色溶液,而铜与稀硫酸不反应,说明铬的活泼性强于铜。(2)Cr(OH)3和Al(OH)3类似,由Al(OH)3的酸式电离可知,Cr(OH)3的酸式电离方程式是:Cr(OH)3H++CrO2-+H2O;(3)电解后溶液中c(Fe3+)=2.0×10-13mol/L,则溶液中c3(OH-)=4×1038/2.0×10-13 =2×10-25,故溶液中c(Cr3+)=6.0×l0-31/2×10-25 =3×10-6mol/L;Ⅱ、C溶液与葡萄糖在加热条件下生成金属D,则D为Ag、C为银氨溶液,气体A与溶液B得到银氨溶液,则A为NH3、B为AgNO3,Ag与溶液H反应得到硝酸银与气体F,则H为HNO3,逆推可知G为NO2,F为NO,E为O2。(1)A为NH3,所含化学键均为极性键,空间构型为三角锥形,属于极性分子; C溶液中的阳离子为[Ag(NH3)2]+;(2)反应①的化学方程式为4NH3+5O2 4NO+6H2O;反应③的离子方程式为3Ag+4H++NO3-=3Ag++NO↑+2H2O。sP的计算、物质的推断及化学方程式的书写。

问答题
阅读理解

Generations of Americans have been brought up to believe that a good breakfast is essential to one's life. Eating breakfast at the start of the day, we have been told, and told again, is as necessary as putting gasoline in the family car before starting a trip.

But for many people, the thought of food as the first thing in the morning is never a pleasure. So in spite of all the efforts, they still take no breakfast. Between 1977 and 1983, the latest year for which figures could be obtained, the number of people who didn’t have breakfast increased by 33%—from 8.8 million to 11.7 million—according to the Chicago-based Market Research Corporation of America.

For those who dislike eating breakfast, however, there is some good news. Several studies in the last few years have shown that, for grown-ups especially, there may be nothing wrong with omitting breakfast. “Going without breakfast does not affect work,” said Arnold E. Bender, former professor of nutrition at Queen Elizabeth College in London, “nor does giving people breakfast improve work.”

Scientific evidence linking breakfast to better health or better work is surprisingly inadequate, and most of the recent work involves children, not grown-ups. “The literature,” says one researcher,  Dr Earnest Polite at the University of Texas, “is poor.”

小题1:The main idea of the passage is that _______.

A.breakfast has nothing to do with people's health

B.a good breakfast used to be important to us

C.breakfast is not as important to us as gasoline to a car

D.breakfast is not as important as we thought before小题2:For those who do not take breakfast, the good news is that _______.

A.several studies have been done in the past few years

B.the omission of breakfast has little effect on one’s work

C.grown-ups have especially made studies in this field

D.eating little in the morning is good for health小题3:The underlined part “nor does giving people breakfast improve work” means  _______.

A.people without breakfast can improve their work

B.not giving people breakfast improves work

C.having breakfast does not improve work, either

D.people having breakfast do improve their work, too小题4:The word "literature" in the last sentence refers to _______.

A.stories, poems, play, etc

B.written works on a particular subject

C.newspaper articles

D.the modern literature of America小题5:What is implied but not stated by the author is that _______.

A.breakfast does not affect work

B.Dr Polite works at an institution of higher learning

C.not eating breakfast might affect the health of children

D.Professor Bender once taught college courses in nutrition in London