已知1mol H2SO4(aq)与1mol Ba(OH)2(aq)反应的△H=-1 584.2kJ•mol-1;稀溶液中,H+(aq)+OH-(aq)═H2O(l)△H=-55.6kJ•mol-1.则Ba2+(aq)+S
(aq)═BaSO4(s)的反应热等于( )O 2-4
A.-1 528.6 kJ•mol-1
B.-1 473 kJ•mol-1
C.+1 473 kJ•mol-1
D.+1 528.6 kJ•mol-1
①2H+(aq)+SO42-(aq)+Ba2+(aq)+2OH-(aq)=BaSO4(S)+2H2O(l)△H=-1584.2kJ•mol-1;
②H+(aq)+OH-(aq)═H2O(l)△H=-55.6kJ•mol-1.
根据盖斯定律,①-②×2得,SO42-(aq)+Ba2+(aq)=BaSO4(S)△H=-1473 kJ•mol-1,
故选B.