某温度下,反应 2CH3OH(g)
CH3OCH3(g)+H2O(g)的平衡常数为400.此温度下,在容积一定的密闭容器中加入CH3OH,反应到某时刻测得各组分的浓度如下:
物质 | CH3OH | CH3OCH3 | H2O |
浓度/(mol•L-1) | 0.44 | 0.6 | 0.6 |
A.CH3OH的起始浓度为1.04mol/L
B.此时逆反应速率大于正反应速率
C.平衡时CH3OH的浓度为0.04mol/L
D.平衡时CH3OH的转化率小于80%
A.由反应2CH3OH(g)
CH3OCH3(g)+H2O(g)可知起始时CH3OH的浓度为0.44mol/L+2×0.6mol/L=1.64mol/L,故A错误;
B.反应到某时刻时浓度商Q=
=c(H2O)×c(CH3OCH3) c2(CH3OH)
=1.86<400,反应未达到平衡状态,向正反应方向移动,则正反应速率大于逆反应速率,故B错误;0.6mol/L×0.6mol/L (0.44mol/L)2
C.设平衡时转化的浓度为x,则
2CH3OH(g)
CH3OCH3(g)+H2O(g)
起始:1.64mol/L O 0
转化:x 0.5x 0.5x
平衡:1.64mol/L-x 0.5x 0.5x
则
=400,x=1.6mol/L,0.5x×0.5x (1.64mol/L-x)2
平衡时CH3OH的浓度为1.64mol/L-1.6mol/L=0.04mol/L,故C正确;
D.平衡时CH3OH的转化率为
×100%=97.6%,故D错误.1.6 1.64
故选C.