问题 计算题

(21分)恒温时,将2molA和2molB气体投入固定容积为2L密闭容器中发生反应:

2A(g) + B(g)  xC (g) + D(s) ,10s时,测得A的物质的量为1.7mol,C的反应速率为0.0225mol·L—1·s—1;40s时反应恰好处于平衡状态,此时B的转化率为20%。请填写下列空白:

(1)x =                  

(2)从反应开始到40s达平衡状态,A的平均反应速率为             

(3)平衡时容器中B的体积分数为                  

(4)该温度下此反应的平衡常数表达式为              数值是     

(5)在相同温度下,若起始时c(A)="5" mol·L-1c(B)=6mol·L-1,反应进行一段时间后,测得A的浓度为3mol·L-1,则此时该反应是否达到平衡状态     (填“是”与“否”),此时v(正)   v(逆)(填“大于”“小于”或“等于”)。

答案

(每空3分)(1)3       (2)0.01mol·L-1·s-1

(3)40%    (4)          0.75

(5)否  大于

(1)10s时生成物C的物质的量是0.0225mol·L—1·s—1×2L×10s=0.45mol,而消耗A是0.3mol,因此根据变化量之比是相应的化学计量数之比可知x=3。

(2)平衡时B的转化率是20%,所以消耗B是0.4mol,则消耗A是0.8mol,所以A的反应速率是

(3)平衡时ABC的物质的量分别是1.2mol、1.6mol、1.2mol,所以C的体积分数为.

(4)平衡常数是指在一定条件下,可逆反应达到平衡状态时,生成物浓度的幂之积和反应物浓度的幂之积的比值,所以表达式为,其数值为

(5)A的浓度变化量时2.0mol/L,所以消耗B是1.0mol/L,生成C是3.0mol/L,此时B的浓度是5.0mol/L,则<0.75,所以没有达到平衡状态,此时正反应速率大于逆反应速率。

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It is said that there are about 40,000 different kinds of jobs in the world. 小题1:“Finding a job ”is not the same as “choosing a job”. Many young people end up in a job which they are not suitable for . 小题2: Here are a few steps to help you think about jobs which you might enjoy doing after school or university.

First , it is important to realize what kind of person you are, which special qualities make you different from everyone else and what you are interested in . 小题3:If you like art and enjoy looking at pictures, this is an interest. But if you can draw a horse that looks like a horse instead of a big dog, that is a skill.

Then ask yourself this question: in the following three areas----skills with people, skills with  information and skills with things-----which are your best skills?

After examining your skills, the next step is research. To find out as many different kinds of jobs as possible, go to the library and read books, magazines and newspapers. 小题4:

Finally, trust your own ideas and your own thinking! 小题5:

A.It is your own life, so find something that you enjoy doing.

B.Choosing the right one itself is a difficult job.

C.We must know what our ideal jobs are.

D.There is a difference between an interest and a skillE. Ask your friends about the work they they do.

F. “Chance” may play a more important part than “decision”.

G. Your parents may also give you some useful advice.