问题 实验题

用中和滴定法测定某烧碱样品的纯度,试根据实验回答下列问题:

(1)准确称量8.2 g含有少量中性易溶杂质的样品,配成500 mL待测溶液。称量时,样品可放

________(填编号字母)称量。

A.小烧杯中          B.洁净纸片上       C.托盘上

(2) 滴定时,用0.2000 mol·L-1的盐酸来滴定待测溶液,不可选用____(填编号字母)作指示剂。

A.甲基橙            B.石蕊             C.酚酞          

(3)在铁架台上垫一张白纸,其目的是_______                           _

(4)用0.20 mol·L-1的盐酸来滴定10.00 mL待测溶液,滴定终止时消耗盐酸溶液20.00mL,计算被测烧碱溶液的物质的量浓度是________mol·L-1,烧碱样品的纯度是________

(5)下列实验操作:将锥形瓶用待测液润洗,然后再加入10.00 mL待测液,则滴定结果          (填“偏高”、“偏低”或“无影响”)。

答案

(1)A(1分) 

(2)B (1分)

(3)便于观察锥形瓶内液体颜色的变化,减小滴定误差(2分)

(4)0.40(2分)  97.56% (2分)      

(5)偏高(1分)

试题解析:(1)烧碱具有强腐蚀性,称量时应该在小烧杯中进行,选A.。

(2) 酸碱滴定的关键就是滴定终点的判断,滴定终点由酸碱指示剂来指示,为了更好的判断滴定终点,我们采用能够由浅色变至深色的指示剂,而不要用油深色变至浅色的指示剂,而且指示剂的变色范围越窄越好。甲基橙的变色范围是3.1~4.4,石蕊的变色范围是5~8,酚酞的变色范围是8~10,用盐酸滴定烧碱溶液时,一般选择甲基橙,也可选择酚酞,但不可选择石蕊 。答案选 B。

(3)在铁架台上垫一张白纸的目的是便于观察锥形瓶内的颜色变化,减小误差。

(4)根据酸碱中和滴定的原理,可计算出待测液的浓度为:0.2mol/L×0.02L/0.01L=0.4mol/L,其烧碱质量为0.4mol/L×0.5L×40g/mol=8g,所以样品的纯度为8g/8.2g×100%=97.56%。

(5)将锥形瓶用待测液润洗,实质上是增加了待测液中得溶质的量,所用标准液体积偏高,使实验结果偏高。

阅读理解

阅读理解。

      As you dash outdoors in the middle of winter, you might make it halfway down the block before realizing

that your ears are freezing because you forgot your hat.

      Now, scientists have shown that even though you've had an apparent memory lapse (丧失), your brain

never forgot what you should have done.

      Memory works mainly by association. For example, as you try to remember where you left your keys,

you might recall you last had them in the living room, which reminds you that there was an ad for soap on

television, which reminds you that you need soap, and so on. And then, as you're heading out of the door to

buy soap, you remember that your keys are on the kitchen counter. Your brain knew where the keys were

all along. It just took a round-about way to get there. 

      Now, scientists at the Salk Institute for Biological Studies are studying associative memory in monkeys

to figure out just how this complicated process works. 

      First, the researchers trained a group of monkeys to remember arbitrary (任意的) pairs of symbols. The

researchers showed the monkeys one symbol (cold weather) and then gave them the choice of two other

symbols, one of which (a hat) would be associated with the first. A correct choice would earn them a sip of

their favorite juice.

      Most of the monkeys performed the test perfectly, but one kept making mistakes.

      "We wondered what happened in the brain when the monkey made the wrong choice, although it

apparently learned the right pairing of symbols," said study leader Thomas Albright.

      Albright and his team observed signals from the nerve cells in the monkey's inferior temporal cortex (ITC),

an area of its brain used for visual pattern recognition and for storing this type of memory.

      As the monkey was deciding which symbol to choose, about a quarter of the activity in the ITC was due

to the choice behavior.

      Meanwhile, more than half the activity was in a different group of nerve cells, which scientists believe

represent the monkey's memory of the correct symbol pairing, and surprisingly, these cells continued to fire

even when the monkey chose the wrong symbol.

      "In this sense, the cells 'knew' more than the monkeys let on in their behavior," Albright said. "Thus,

behavior may vary, but knowledge endures."

1. The example of the keys and soap is given to explain the relationship between ______. [ ]

A. memory lapse and human brain

B. memory and association

C. memory and television ads

D. memory and our daily life

2. Which of the following best expresses the general idea of the text? [ ]

A. Your brain may forget something, but not always.

B. Activity is a round-about way to memory.

C. Your brain remembers what you forget.

D. Monkeys have better memory than us.

3. The researchers believe the monkey that made the wrong choice ______. [ ]

A. also knew the correct answer

B. had the worst memory

C. failed to see the objects well

D. had some trouble with its nerve system

4. The underlined word "endures" may be best replaced by ______. [ ]

A. disappears

B. increases

C. improves

D. remains

单项选择题