问题
填空题
由金红石(TiO2)制取单质Ti,涉及到的步骤为:TiO2→TiCl4
Ti已知:①C(s)+O2(g)=CO2(g);△H=-393.5kJ•mol-1②2CO(g)+O2(g)=2CO2(g);△H=-566kJ•mol-1③TiO2(s)+2Cl2(g)=TiCl4(s)+O2(g);△H=+141kJ•mol-1,则TiO2(s)+2Cl2(g)+2C(s)=TiCl4(s)+2CO(g)的△H=______kJ/mol.镁/800℃/Ar
答案
根据盖斯定律①×2-②+③得
TiO2(s)+2Cl2(g)+2C(s)=TiCl4(s)+2CO(g)△H=(-393.5kJ•mol-1)×2-(-566kJ•mol-1)+(+141kJ•mol-1),
即TiO2(s)+2Cl2(g)+2C(s)=TiCl4(s)+2CO(g)△H=-80kJ/mol,故答案为:-80.