问题 填空题

一定温度下2L的恒容容器甲中,加入2moL碳和2moLCO2发生如下反应: C(s)+CO2(g) 2CO(g) △H>0

测得容器中CO2的物质的量随时间t的变化关系如图所示。

(1)该反应的ΔS   0(填“>”、“<”或“=”)。在   (填“较高”或“较低”)  温度下有利于该反应自发进行。

(2)列式并计算上述温度下此反应的平衡常数K          。(结果保留一位小数)

(3)向上述平衡体系中再通入CO2,则CO2的转化率    (填增大、减小、不变、无法确定)。

(4)相同温度下,2L的恒容容器丙中加入4moL碳、4moLCO2和4moLCO。开始反应时v(正)     v(逆)(填>、 <、﹦)。

(5)相同温度下,2L的恒容容器乙中加入4moL碳和4moLCO2,达到平衡。请在图中画出乙容器中CO2的物质的量随时间t变化关系的预期结果示意图。(注明平衡时CO2的物质的量)

答案

(1)>  较高(2分,各1分)

(2)K=c2(CO)/c(CO2)=1.242/0.38="4.0" (3分)

(3)减少(2分)

(4) >(2分)

(5)如图 (3分)

题目分析:(1)生成物中气体的化学计量数之和大于反应物中气体的化学计量数之和;该反应为吸热反应;

(2)平衡常数是指可逆化学反应达到平衡时,每个产物浓度系数次幂的连乘积与每个反应物浓度系数次幂的连乘积之比;

(3)通入二氧化碳使其浓度增大,平衡向右移动,但其的转化率降低;

(4)因为所以平衡向右移动,正反应速率大于逆反应速率;

(5)因为的浓度增大,所以反应速率加快,达到平衡的时间减少,设消耗Xmol,则有

阅读理解

Q:

I’d like to know about fluency.What can I do to feel better when I’m talking to other people? Do you have some ways to learn it faster? Please help me!   —Roberto in Brazil

A:

Roberto wants to know how to become more fluent in English, and this is something you want to be able to do “fast”.

First, if you get to meet English speakers much, the important rule is to listen not just to native speakers of English, but also to very good users of English.If you don’t, then listen to the radio, TV or films in English.

The next step is to notice what it is that speakers of English do, which makes them sound fluent.The first trick(诀窍) is to probably have confidence.Some people think they might make mistakes.Don’t worry about that.Your listeners will usually try hard to understand you — a few grammar mistakes aren’t going to worry them.

What you do need to worry about is pronunciation, especially stress(重音).When you learn a new word or expression, learn it with its stress.Notice how a native speaker says it or look it up in a dictionary.

Another good thing that speakers of English do is to have a few tricks up their sleeves(袖子) for when they need to give themselves thinking time.Sometimes they use “filler sounds” like er, um and so on.

It is also useful to know how to bring other speakers into your conversation so that you keep them interested - and this is often done by asking questions like “What do you think?” “How do you feel about this?” and so on.

So, to become a fluent speaker, you’ll need to put into practice all these kinds of things.And there’s the key: practise, practise, practise.             -Susan Fearn

56.Susan first encourages English learners to      .

A.meet English speakers     B.listen to very good speakers

C.talk to English speakers   D.buy a radio or a TV set

57.When mentioning pronunciation, Susan pays special attention to   .

A.stress B.expressions      C.dictionaries      D.words

58.What do the underlined words “to have a few tricks up their sleeves” probably mean?

A.To wear a lot of clothes.                   

B.To have a secret plan or idea.

C.To hide some tricks into their sleeves. 

D.To have sleeves covering their whole arms.

59.What do we know from the passage?

A.One can only learn stress from dictionaries.

B.Grammar mistakes worry one’s listeners a lot.

C.Asking questions can make one’s conversation attractive.

D.One can become fluent if one practises one of the suggestions.

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