问题 填空题

长期以来一直认为氟的含氧酸不存在。但是1971年斯图杰尔和阿佩里曼(美)成功地合成次氟酸后,这种论点被剧烈地动摇了。他们是在0℃以下将氟化物从细冰末的上面通过,得到毫克量的次氟酸。

(1)以下两种结构式,能正确地表示次氟酸的结构的是____,理由是_________________。

A.H-O-F B.H-F-O

(2)次氟酸中氧元素的化合价为____价,次氟酸的电子式为____,次氟酸的分子中共价键的键角____(填“>”、“<”或“=”)180°。

(3)下表给出了几种分子和基团中化学键的键能

请计算反应2HOF=2HF+O2的反应热(△H)的近似值为_______kJ/mol。请从计算结果预测次氟酸的化学性质_________________。

答案

(1)A;A项中O和F的最外层电子数等于8,B项中O 和F的原子最外层电子数不等于8

(2)0;;<;

(3)-253;次氟酸不稳定,易分解为HF和O2

单项选择题 A1/A2型题
单项选择题

As NASA prepares to set twin robots loose on the Martian surface and makes plans to send another in 2007, the agency’s long term goal is clear: determine whether the red planet does or ever did harbor life.

But the current search for life is necessarily limited to life as we know it, organisms dependent on liquid water. A SPACE. corn reader recently suggested that "We as humans are arrogant, simply believing that any other form of life will be just like us. "

Researchers devoted to the search for extraterrestrial (ET) have a similar view. "Scientists’ approach to finding life is very Earth-centric," says Kenneth Nealson, a geobiologist at the University of Southern California. "Based on what we know about life on Earth, we set the limits for where we might look on other planets," Nealson said. Within that framework, however, there are extreme cases of life on Earth that suggest the range of places to look on frigid Mars.

Nealson and his colleagues recently found the most extreme sort of organism in a salty liquid lake under the permafrost of Siberia. The organism, named cryopegella, can exist at colder temperatures than any previously discovered. Nealson’s team figures that if the ice at the polar caps of Mars warmed to liquid water, organisms like cryopegella could have awakened and repaired any damage that might have occurred to their various cellular components. That does not mean there are necessarily dormant microbes within the ice caps of Mars. But it does suggest a broader range of potential cradles for life.

Other researchers agree, and a host of so-called "extremophile" discoveries on Earth in recent years indicate the polar regions of Mars might be prime hunting grounds. As on Earth, organisms there might be slathered in natural antifreeze or be able to go dormant for tens of thousands of years, waiting for a brief thaw, their moment in the Sun.

Meanwhile, scientists recognize that there could indeed be life elsewhere in the universe that does not require water. And some astrobiologists are trying to explore the possibilities. But it is a tough problem to approach. In looking for "life as we don’t know it," it’s hard to even imagine what to expect.

Life might or might not exist on Mars. If there are critters there, they might or might not be like bacteria on Earth. In laboratory conditions, scientists in 2001 were able to get one-celled organisms to incorporate an amino acid—a fundamental building block of life—that no other known life uses. The discovery borders on the creation of artificial life, experts said. It also suggests that ET might operate by entirely different rules than those we’re used to.

If life on Mars is fundamentally different from what scientists understand life to be, then current spacecraft and others in the works may well not recognize what’s right under their mechanical noses.

The purpose of the author mentioning scientists’ laboratory creation in 2001 is to emphasize the idea that ().

A. it is hard to imagine what ET is really like

B. life might or might not exist on Mars

C. it is possible to create artificial life

D. Martians may live by entirely different rules