问题
选择题
已知H—H键的键能为436kJ/mol,N—H键的键能为391kJ/mol,根据热化学方程式:N2+3H2=2NH3△H ="-" 92.4 kJ/mol可得N≡N键的键能是( )
A.431 kJ/mol
B.945.6 KJ/mol
C.649 kJ/mol
D.869 kJ/mol
答案
答案:B
△H =反应物的键能之和—产物的键能之和=N≡N键的键能+3×436kJ—6×391kJ="-" 92.4 kJ,得:N≡N键的键能为945.6 KJ/mol,选B