问题 填空题

以富含硫酸亚铁的工业废液为原料生产氧化铁的工艺如下(部分操作和条件略):

Ⅰ从废液中提纯并结晶出FeSO4·7H2O;

Ⅱ将FeSO4·7H2O配制成溶液;

ⅢFeSO4溶液与稍过量的NH4HCO3溶液混合,得到含FeCO3的浊液;

Ⅳ将浊液过滤,用90℃热水洗涤沉淀,干燥后得到FeCO3固体;

Ⅴ煅烧FeCO3,得到Fe2O3固体。

已知:NH4HCO3在热水中分解。

(1)Ⅰ中,要加足量的铁屑除去废液中的Fe3+,该反应的离子方程式是_______________。

(2)Ⅱ中,需加一定量硫酸.运用化学平衡原理简述硫酸的作用____________________。

(3)Ⅲ中,生成FeCO3的离子方程式是_________________,若FeCO3浊液长时间暴露在空气中,会有部分固体表面变为红褐色,该变化的化学方程式是______________________。

(4)Ⅳ中,通过检验SO42-来判断沉淀是否洗涤干净,检验SO42-的操作是_________________________________________________。

(5)已知煅烧FeCO3的化学方程式是4FeCO3+O22Fe2O3+4CO2,现煅烧464.0 kg的FeCO3,得到316.8 kg产品,若产品中杂质只有FeO,则该产品中Fe2O3的质量是________kg。(摩尔质量/g·mol-1:FeCO3 116 Fe2O3 160 FeO 72)

答案

(1)Fe+2Fe3+===3Fe2+

(2)加入硫酸,H+浓度增大,使Fe2++2H2OFe(OH)2+2H+的平衡向逆反应方向移动,从而抑制Fe2+的水解

(3)Fe2++2HCO3-===FeCO3↓+CO2↑+H2O;4FeCO3+6H2O+O2===4Fe(OH)3↓+4CO2

(4)取少量洗涤后的溶液放入试管中,滴加盐酸酸化的BaCl2溶液,若无白色沉淀产生,则沉淀洗涤干净

(5)288.0

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All modern human originated in sub-Saharan Africa, according to a new study boasted by its founders as the "final blow" against an opposing viewpoint. Not so fast, says one anthropologist who finds flaws in the evidence.

The new study, published in the July 19 issue of the journal Nature, delivers what the researchers say could be the final verdict in support of the single point "Out of Africa" theory.

Manica and colleagues took multiple measurements of more than 4,500 male fossil skulls from 105 populations around the globe. They combined the results with data from studies of global genetic variations in humans, finding that both genetic and skull variability decreased with distance from Africa. So populations in southeastern Africa held the highest variability compared with populations in other countries.

The results held even when the scientists accounted for climate, since climate conditions can lead to changes in skull features. " In very cold climates you tend to generate a slightly thicker brow ridge. Whether or not that’ s to keep horrible blizzards out of your eyes, I don’ t know, " Amos said.

Past studies based on skull morphology have been weak and have supported both of the humanorigin views.

In his own research, Hawks is funding that natural selection has led to changes in thousands of genes during only the past few thousand years.

"I’ m really thinking just the opposite of this paper, " Hawks said. "There are differences in the skull between populations, including their variability, but it is mostly due to very recent effects and not the origin of modern humans. "

"The muhiregional idea is identical to the recent African origin idea, except for its prediction that Europeans and Asians were part of the single population of origin and didn’t become extinct. "

[A] "Humans seem to have poured out of Africa, spread out across the world, but at a really quite uniform rate such that you get this lovely gradual loss of diversity," said study team member William Amos of the University of Cambridge.

[B] All modern humans originated from the same ancestors and they kept evolving as the society advances. Some species died out but others remained to live on the earth, which is still impossible to solve.

[C] At the end of the day, a resolution to the " Out of Africa" debate may be impossible, he said. Most of the evidence can be interpreted as supporting both human-origins theories. "It’ s really hard to find the two," Hawks said.

[D] This study " adds a p line of evidence to the Out of Africa (hypothesis) using such morphology," said paleontologist Will Harcourt-Smith of the American Museum of Natural History in New York. Harcourt-Smith was not involved in the current research.

[E] Debate over the origins of modern humans has simmered among anthropologists for years, with one theory asserting that Homo sapiens migrated across the world from a single point in Africa. The other theory states that multiple populations of Homo sapiens independently evolved from Homo erectus in regions beyond Africa.

[F] The recent study was funded by the Biotechnology and Biological Sciences Research Council. It has provided conclusive evidence concerning the actual process of human evolution.

[G] "We have combined our genetic data with new measurements of a large sample of skulls to show definitely that modern humans originated from a single area in sub-Saharan Africa," said lead researcher Andrea Manica of the University of Cambridge.

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