问题 填空题

A、B、C、D、E 5种短周期元素,A元素所处的周期数、主族序数、原子序数均相等;B的原子半径是其所在主族中最小的,B的最高价氧化物对应水化物的化学式为HBO3;C元素原子的最外层电子数比次外层多4个;C的阴离子与D的阳离子具有相同的电子层结构,两元素可形成化合物D2C;C、E 同主族.

(1)B在周期表中的位置第______周期,第______族;

(2)C、E 两种元素可能形成化合物的化学式______;

(3)化合物BC与C2反应的化学方程式______;

(4)1.6gB2A4液体与C2气体反应生成B2气体和液态A2C,放出31.05kJ的热量,写出1molB2A4反应的热化学方程式:______.

答案

由短周期元素,A元素所处的周期数、主族序数、原子序数均相等,则A为氢元素;B的原子半径是其所在主族中最小的,B的最高价氧化物对应水化物的化学式为HBO3,则B为氮元素;C元素原子的最外层电子数比次外层多4个,则K层电子为2,L层电子为6,即C为氧元素;C、E 同主族,则E为硫元素;C的阴离子与D的阳离子具有相同的电子层结构,两元素可形成化合物D2C,D的最外层电子为1,质子数为11,则D为钠元素,

(1)B为氮元素在第2周期,最高价为+5价,则在第ⅤA 族,故答案为:2;ⅤA;

(2)C为氧,E为硫,S有+4、+6两种常见的正化合价,则二者形成常见的化合物为SO2或SO3,故答案为:SO2或SO3

(3)NO与氧气在常温下反应生成二氧化氮,该反应为2NO+O2=2NO2,故答案为:2NO+O2=2NO2

(4)B2A4为N2H4,与氧气反应生成氮气和水,1.6gB2A4液体与C2气体反应放出31.05kJ的热量,则1molB2A4液体与C2气体反应放出热量为31.05kJ×

32
1.6
=621.0KJ,则热化学方程式为

N2H4(l)+O2(g)=N2(g)+2H2O(l)△H=-621.0 kJ•mol-1

故答案为:N2H4(l)+O2(g)=N2(g)+2H2O(l)△H=-621.0 kJ•mol-1

听力题

请认真阅读下面短文,并根据各题所给首字母的提示,写出一个合适的英语单词完整、正确的形式,使短文通顺。

A man walked 小题1:i_______ a doctor's examining room. “Put out your tongue (舌头) ,” the doc­tor said. The man put out his tongue, and the doctor looked at it quickly.

“OK, you can put your tongue小题2:b________ now,” the doctor said. “It's clear what's wrong with you. You need more exercise.”

“But, doctor,” the man said. “I don't think …”

“Don't tell me what you think,” the doctor said, “I am the doctor, not you. I know what you need. I see hundreds of people like you. 小题3:N________ of them get any exercise. They sit in offices all day and in 小题4:f________ of the TV in the evening. What you need is to walk quickly for at 小题5:l________ 20 minutes a day.”

“Doctor, you don't understand,” the patient said. “I…”

“I don't want to hear any小题6:e________,” the doctor said. “You must find time for exercise. If you don't, you will get fat and have小题7:h________ problems when you are older.”

“But I walk every day.” the patient said.

“Oh, yes, and I know that. You walk a few feet from your house to your office, or a few more feet from your office to a restaurant, etc. That is not real walking. I'm talking about a walk in the park for twenty minutes every day.”

“Will you listen to me, doctor!” the patient 小题8:s________, getting angry with the doctor who thought he knew小题9:e________. “I'm a postman,” the patient went on. “and I walk for seven hours every day!”

For a moment the doctor was silent, then he said quietly, “Put your tongue out 小题10:a________, will you?”

单项选择题