问题 填空题

(12分)T、X、Y、Z、Q、R、W为周期表前四周期的元素,原子序数依次递增。已知:

①W的原子序数为29,其余元素均为短周期主族元素;

②T原子所处的周期数、族序数分别与其原子序数相等;

③X的基态原子电子占据三种能量不同的轨道,且每种轨道中的电子数相同;

④Z的基态原子价电子排布为ns2npn+2

⑤在该元素所在的周期中,Q的基态原子的第一电离能最小;

⑥R的单质常温常压下是气体,其基态原子的M层上有1个未成对的p电子;

(1)X、Y、Q三种元素的电负性由大到小的顺序是                  (用元素符号表示)。

(2)与W同周期的元素中,原子最外层电子数与W元素原子相同的元素还有     (填元素符号)。由W2+制取[W(YT3)4]2+的离子方程式为                           

(3)T、X、Z三种元素组成的一种化合物M是蚂蚁分泌物和蜜蜂的分泌液中含有的物质,俗称蚁酸,它的分子式为XT2Z2,则该分子的X原子采取         杂化,1mol M分子中δ键和π键的个数比为         

(4)X和Y原子结合形成的X3Y4晶体,其晶体结构与金刚石类似,但硬度比金刚石大,其原因是                                                 

答案

(1)N>C>Na(2分)

(2)K、Cr(2分);Cu2++4NH3·H2O="==" [Cu(NH3)4 ]2++4H2O(2分)

(3)sp2(2分);4:1(2分)

(4)氮原子半径小于碳,氮碳形成的共价键键长更短,键能更大,键更稳定(2分)

考查原子核外电子排布规律、元素周期律、化学键以及晶体类型的判断等。

根据①可知W是铜。根据②可知T是H。根据③可知X是C。金属性越强,第一电离能越小,所以根据⑤可知Q是Na。根据⑥可知R是Cl。Z的原子序数介于C和Na之间,所以根据④可知Z是O,Y的原子序数大于C的,小于O的,则Y只能是N。

(1)非金属性越强,电负性越大,因此是N>C>Na。

(2)根据构造原理可知铜原子的最外层电子数是1,在第四周期中满足最外层电子数为1的还有K和Cr。[Cu(NH3)4 ]2+是通过配位键形成的离子,所以反应的方程式为Cu2++4NH3·H2O="==" [Cu(NH3)4 ]2++4H2O。

(3)蚁酸的结构简式为HCOOH,结构式为,所以碳原子采取的是sp2杂化。因为双键是由1δ键个和1个π键组成的,所以该化合物中δ键和π键的个数之比是4:1。

(4)金刚石是原子晶体,所以C3N4晶体也是原子晶体。形成原子晶体的共价键越强,硬度越大。由于氮原子半径小于碳原子半径,所以碳和氮形成的共价键强于碳和碳形成的共价键,所以硬度更大。

阅读理解

阅读理解。

     John "Mad Jack" Mytton (1796-1834) was a carefree English aristocrat who was born into

immense wealth. However, he died a poor man after a life that was once described as "a series of

suicide attempts". So, what went wrong?

     As a young boy, Jack went to Westminster School, but after only one year he was expelled for

fighting with a teacher. He was then sent to Harrow School but only lasted three days before he was

also thrown out. He was eventually educated by private tutors.

     After school, Jack went to Cambridge University. He arrived with 2,000 bottles of port, but left

without graduating - he found university life boring. Later, he joined the army, enlisting with the 7th

Hussars. As a young officer, he spent a year with the regiment in France as part of the occupation

force after Napoleon's defeat in 1815. Jack passed the time gambling and drinking before resigning

his commission. At the age of 21, he returned to his country house just in time to receive his inheritance.

     With an annual income of over £800,000 in today's money, Jack was extremely rich… but it didn't

take him long to spend it all. In 1819, he became an MP. In order to secure his seat, he offered voters

£10 notes to vote for him, spending more than £10,000 in total. However, he found politics dull and

went to parliament only once. Back at home, he would often drop bank notes in the gardens of his

estate, and gave his servants vast amounts of spending money. Once he lost his racetrack winnings

(several thousand pounds) when the wind blew all the money away.

     One of Jack's favorite pastimes was hunting. He would go in any kind of weather, occasionally

with no clothes on. Sometimes, he would get up in the middle of the night, take off with a gun to look

for something to shoot.

     Jack also kept a large number of pets. These included about 2,000 dogs. Some were fed on steak

and Champagne and even wore livery. A favorite horse had free range inside Halston Hall and would

often lie with Jack in front of the fire.

     Jack was a bit of a practical joker, too. He once left a horse in the bedroom of a guest. Another

visitor fell asleep and woke up to find a live bear and two bulldogs in his bed. In 1826, as a result of a

bet, Jack rode his horse into the Bedford Hotel, up the grand staircase and onto the balcony. Then,

still sitting on the horse, he jumped off the balcony, landing among the diners in the restaurant below.

     Another time, he invited a local doctor to dine at Halston Hall. As soon as the doctor had left,

Jack put on a highwayman's costume and raced ahead to rob the unsuspecting man. On another

occasion, a passenger in Jack's carriage admitted that he'd never been in an accident, so Jack drove

the carriage up a hill and turned it over. He would also slip red-hot coals into people's pockets as a

joke.

     Eventually, Jack ran out of money and fell into debt. In 1830, he fled to France to avoid his

creditors(债主), but returned a couple of years later, ending up in prison in Southwark, London. Jack

died there in 1834, a poor, lonely man.

1. It can be inferred in the passage that ________.

A. Jack was first educated by private tutors and eventually graduated from Cambridge University.

B. Jack joined the army and succeeded in defeating Napoleon's army in 1815.

C. Jack bribed the voters in order to gain a position of MP.

D. Jack fed his favorite horse with meat and wine and often lay with it in front of the fire.

2. Once Jack rode his horse into a grand hotel and jumped off the balcony in order to pay for his _____.

A. bet        

B. debt        

C. joke        

D. gambling

3. The examples in paragraph 7 tell us that _______.

A. Jack was always ready to help people experience what they hadn't experienced.

B. Jack always punished people by all means to let out his hatred.

C. Jack always played tricks on people to have fun.

D. Jack went mad and treated people unfriendly and even cruelly.

4. The word _________ would be more proper to describe Jack's life.

A. ridiculous    

B. luxurious      

C. tricky    

D. greedy

5. By writing "a series of suicide attempts" in paragraph 1, the author probably means that ________.

A. Jack attempted to kill himself because he was too poor.

B. Jack pretended to suicide to avoid his creditors.

C. Jack lost his life in fighting with poverty.

D. All that Jack had did in his life contributed to his own failure and poverty.

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