问题 填空题

(10分)钛白粉(主要成分是Ti02),覆盖能力强,折射率高,无毒,广泛用于油漆、塑料、造纸等行业,还可用作乙醇脱水、脱氢的催化剂。下图是以钛铁矿(主要成分FeTi03,钛酸亚铁)为主要原料生产钛白粉的工艺流程图,回答下列问题:

(1)上述生产流程中加入物质A的目的是防止Fe2+被氧化,物质A是   ;上述制备Ti02的过程中,所得到的副产物是   ,可回收利用的物质是:___________________。

(2)写出TiOS04溶液在加热条件下水解反应的离子方程式:                  

(3)为测定TiOS04的含量,首先取待测钛液10 mL用水稀释至100 mL,加过量铝粉,充分振荡,使其完全反应:3Ti02+ +Al+6H+==3Ti3++AL3++3H20。过滤后,取出滤液20 mL,向其中滴加2~3滴KSCN溶液作指示剂,用酸式滴定管滴加0.1mol·L-1 FeCl3溶液,当溶液出现红色达到滴定终点,用去了30mL FeC13溶液。待测钛液中TiOS04的物质的量浓度是____________________。

答案

(10分)

(1)铁粉  FeSO4?7H2O  H2SO4

(2)TiO2++2H2O=H2TiO3↓+2H+

(3)1.5 mol?L-1

(1)因Fe2+易被氧气氧化生成Fe3+,为防止Fe2+被氧化,物质A是铁粉,其反应原理为:2Fe3++ Fe=3Fe2+;同时不会引入新的杂质;

制备Ti02的过程中,所得到的副产物是:FeSO4?7H2O ;可回收利用的物质是:H2SO4

(2)TiOS04溶液在加热条件下水解反应的离子方程式可由流程图得知,Ti以H2TiO3沉淀的形式出现,即方程式为:TiO2++2H2O=H2TiO3↓+2H+

(3)反应的离子方程式为:Fe3++Ti3+=Fe2++Ti4+;Fe3+与Ti3+以1:1的形式反应,,即20 mL滤液中,由Ti元素守恒可知,则100 mL滤液中

待测钛液中TiOS04的物质的量浓度是

单项选择题
单项选择题

There are many kinds of friends. Some are always (1) you, but don’t understand you. Some say only a few words to you, but understand you. Many people will step in your life, but only (2) friends leave footprints.

I shall always recall the autumn and the girl with the (3) . She will always bring back the friendship between us. I know she will always be my best friend.It was the golden season. I could see the yellow leaves (4) with the cool (5) . In such a season, I liked walking alone on the roads covered with leaves, (6) to the sound of them.Autumn is a (7) season and life is uninteresting. The free days always get me (8) . But one day, the sound of a violin (9) into my ears like a stream flowing in the mountains. I was so surprised that I jumped to see what it was. A young girl, standing in the wind, was (10) in playing her violin.

I had (11) seen her before. The music was so nice that I listened quietly. Lost in the music, I didn’t know that I had been (12) there for so long but my existence did not seem to disturb her.Leaves were still falling. Every day she played the violin at the comer of the building (13) I went downstairs to watch her performance. I was the only listener. The autumn seemed no longer lonely and life became (14) . (15) we didn’t know each other, I thought we were already good friends. I believe she also loved me.Autumn was nearly over. One day, when I was listening carefully, the sound suddenly (16) . To my astonishment, the girl came over to me.

"You must like music from the violin." she said."Yes. And you play very well. Why did you stop’." I asked.Suddenly, a (17) expression appeared on her face and I could feel something unusual."I came here to see my grandmother, but now I must leave. I once played very badly. It was your listening every day that (18) me. " she said."In fact, it was your playing (19) gave me a meaningful autumn," I answered, " Let’s be friends. "The girl smiled, and so did I. I never heard her play again in my life. I no longer went downstairs to listen to her. Only thick leaves were left behind. But I will always remember the fine figure of the girl. She is like a (20) —so short, so bright, like a shooting star giving off so much light that makes the autumn beautiful.

第(19)空应选择()

A.that 

B.which 

C.it 

D.who