问题 计算题

某稀溶液中含4molKNO3和2.5molH2SO4,向其中加入1.5molFe粉,充分反应后产生的气体在标况下的体积为( )

A.36L

B.28L

C.22.4L

D.11.2L

答案

答案:B

题目分析:因为硝酸有强氧化性,铁没有过量的情况下,没机会成生亚铁。

反应如下:

Fe + 4HNO3 = Fe(NO3)3 + NO↑ + H2O

如果铁过量,有机会发生:

Fe + 2Fe(NO3)3 = 3Fe(NO3)2

题目中,整个过程都是发生:

Fe + 4HNO3 = Fe(NO3)3 + NO↑ + H2O--------(1)这个反应的。

根据题目中硝酸钾与硫酸的量,可知,溶液中有4摩尔硝酸。

第一次反应,4摩尔硝酸与1摩尔铁反应,生成1摩尔硝酸铁和1摩尔NO。

生成的1摩尔硫酸铁与剩余的1摩尔氢离子又得到1摩尔的硝酸,再与剩下的0.5摩尔铁,再发生:

Fe + 4HNO3 = Fe(NO3)3 + NO↑ + H2O--------(2)

因为硝酸只有1摩尔,又没有氢离子补充,所以(2)这个反应,只有0.25摩尔铁参加,再生成0.25摩尔NO.

这样气体总物质的量生成1.25mol ,体积是28升。

然后剩余的0.25mol铁,与硝酸铁再发生:

Fe + 2Fe(NO3)3 = 3Fe(NO3)2这个反应。

反应到此结束.

点评:此题要注意反应的实质。是硝酸根和氢离子与金属的反应。只要能提供硝酸根和氢离子反应就能进行。

单项选择题 案例分析题
单项选择题

Disability among the elderly has declined markedly in the United States in the past two decades. In 1984, 25 percent of the elderly population reported difficulty with activities associated with independent living. By 1999, the share had fallen to 20 percent, a decline of one-fifth. Although these basic facts are well known, their interpretation is not clear. Is the reduction in disability a result of improved medical care, individual behavioral changes, environmental modifications that allow the elderly to better function by themselves, or other demographic changes Will the trend continue, or is it time limited What does the reduction in disability mean for years of healthy life and labor force participation

The researchers David Cutler, Mary Beth Landrum, and Kate Stewart focus on disability caused by cardiovascular disease to investigate the role of improved medical care on reductions in disability. By looking at just one condition, they can analyze health shocks and their outcomes in some detail. Cardiovascular disease is a natural condition to analyze, because it is the most common cause of death in the United States and most other developed countries. Also, more is spent on cardiovascular disease than on any other condition, clearly a case where medical care could really matter.

The researchers measure disability as the presence of impairments in. Activities of Daily Living (ADLs) and Instrumental Activities of Daily Living (IADLs). Their data source, the National Long-Term Care Survey(NLTCS) , includes information on six ADL measures: eating, getting in or out of bed, walking around inside, dressing, bathing, and getting to or using the toilet. There are also questions about eight IADL measures: doing light housework or laundry, preparing meals, shopping for groceries, getting around outside, managing money, taking medications, and making telephone calls. The NLTCS is a nationally representative longitudinal survey of the health and disability profile of the population aged 65 and over.

Cutler and his co-researchers find that reduced disability associated with cardiovascular disease accounts for a significant part of the total reduction in disability--between 14 and 22 percent. The evidence suggests that improvements in medical care, including both increased use of relevant procedures and pharmaceuticals, led to a significant part of this decline in disability. Regions with higher use experienced substantial reductions in mortality and disability.

While precise data on the implications of reduced disability are lacking, the possible impact of disability reductions is staggering. The researchers estimate that preventing disability after an acute cardiovascular event can add as much as 3.7 years of quality-adjusted life expectancy, or perhaps $ 316,000 of value. The cost of this outcome is significantly smaller. The initial treatment costs range from $ 8,610 to $ 16,332, depending on the procedure used. Further, recent cost analyses reported that annual Medicare spending was lower for the non-disabled than the disabled, which suggests that higher treatment costs may be offset by lower future spending among a more healthy population. By virtually any measure, therefore, the researchers conclude that medical technology after acute cardiovascular episodes is worth the cost.

We can learn from paragraph 3 that()

A. ADLs and IADLs share the same measures

B. measures of IADLs seem to be more complex than those of ADLs

C. NLTCS provides information only for IADLs

D. NLTCS provides information only for ADLs