问题 问答题

我国目前使用碘酸钾作为食用盐中碘强化剂.并规定,食用盐碘含量的平均水平(以碘元素计)为20mg/kg~30mg/kg.

(1)碘酸钾与碘化钾在酸性条件下发生如下反应,配平化学方程式,并用单线桥标出电子转移.

______KIO3+______KI+______H2SO4=______K2SO4+______I2+______H2O

(2)已知:I2+2S2O32-=2I-+S4O62-,某学生测定食用精制盐的碘含量,其步骤为:

a.准确称取20g食盐,加适量蒸馏水使其完全溶解;

b.用稀硫酸酸化所得溶液,加入足量KI溶液,使KIO3与KI反应完全;

c.以淀粉为指示剂,逐滴加入物质的量浓度为2.0×10-3mol-L-1的Na2S2O3溶液10.0mL,恰好反应完全.

①判断c中反应恰好完全依据的现象是______.

②b中反应所产生的I2的物质的量是______mol.

③根据以上实验和包装袋说明,所测精制盐的碘含量是______mg/kg.

答案

(1)该反应中化合价的变化为:KIO3→I2,I元素由+5价→0价,一个KIO3分子得5个电子;KI→I2,I元素由-1价→0价,一个KI分子失一个电子,所以得失电子的最小公倍数为5,KIO3的计量数为1,KI的计量数为5,其它元素根据原子守恒配平.故答案为:

(2)①I2+2S2O32-=2I-+S4O62-,碘遇淀粉变蓝色,溶液中没有碘,溶液为无色,故答案为:溶液由蓝色恰好变为无色;

②I2+2S2O32-=2I-+S4O62-

         1mol  2 mol

    1.0×10-5mol 2.0×10-3mol?L-1×0.01L

故答案为:1.0×10-5

③KIO3+5KI+3H2SO4=3K2SO4+3I2+3H2O

 碘酸钾中的碘  127g                                3mol

           

127
3
×10-5g                           1.0×10-5mol

设每千克食盐中含碘xmg,列比例式为

127
3
×10-2mg:0.02kg=xmg:1kg

x=21,故答案为:21.

完形填空
At the beginning of this century, medical scientists made an interesting discovery: we are built not just of flesh(肌肉) and blood but also of time. They were   41  to show that we all have a ‘body clock’   42  us, which controls the   43  and fall of our body energies,   44  us different from one day to the next.
The   45  of a ‘body clock’ should not be too   46  since the lives of most living things are controlled   47  the 24-hour night-and-day cycle(循环). We feel   48  and fall asleep at night and become   49  and energetic during the day. If the 24-hour cycle is   50  most people experience unpleasant   51 . For example, people who are not   52  to working at night can find that   53  of sleep causes them to   54  badly at work.
  55  the daily cycle of sleeping and   56 , we also have other cycles which   57  longer than one day. Most of us would   58  that we feel good on some days and not so good on   59 ; sometimes our ideas seem to flow and at other times, they   60  do not exist.
小题1:
A.anxiousB.carefulC.ableD.proud
小题2:
A.aroundB.insideC.betweenD.on
小题3:
A.riseB.supplyC.useD.movement
小题4:
A.showingB.treatingC.changingD.making
小题5:
A.ideaB.opinionC.storyD.invention
小题6:
A.difficultB.excitingC.interestingD.surprising
小题7:
A.fromB.overC.byD.during
小题8:
A.dull B.dreamy C.tired D.peaceful
小题9:
A.regularB.excitedC.clearD.lively
小题10:
A.shortenedB.disturbedC.resetD.troubled
小题11:
A.momentsB.sensesC.feelingsD.effects
小题12:
A.usedB.allowedC.expectedD.prevented
小题13:
A.missB.noneC.needD.lack
小题14:
A.showB.performC.manageD.control
小题15:
A.WithB.ExceptC.As well asD.Rather than
小题16:
A.waking B.movingC.livingD.working
小题17:
A.repeatB.remainC.happenD.last
小题18:
A.believeB.agreeC.realizeD.allow
小题19:
A.othersB.the otherC.all otherD.other
小题20:
A.onlyB.justC.stillD.yet
单项选择题