问题 实验题

(12分)某化学研究性学习小组探讨Fe3+和SO32-之间发生怎样的反应,请你一起参与并协助他们完成实验。

⑴提出猜想:

甲同学认为发生氧化还原反应,其反应的离子方程式为               

乙同学认为发生双水解反应,其反应方程式为2Fe3++3SO32-+6H2O=2Fe(OH)3(胶体)+3H2SO3

⑵实验验证:

丙同学设计了下列实验来探究反应的可能性。

①为了检验所用Na2SO3是否变质,应选用的试剂是                   

②取5mLFeCl3溶液于试管中,逐滴加入Na2SO3溶液至过量,观察到溶液颜色由黄色变为红棕色(无气泡产生,也无沉淀生成)。

③将②溶液分成两等份,其中一份加入稀盐酸至过量,再加入BaCl2稀溶液,有白色沉淀生成;另一份滴入几滴KSCN溶液,溶液变成血红色。

⑶得出结论:

①根据丙同学的实验得出的结论是:                               

②实验③中溶液变成血红色的离子方程式为                        

⑷拓展探究:

①丁同学在FeCl3溶液中加入Na2CO3溶液,观察到红褐色沉淀并且产生无色气体,该反应的离子方程式是                                   

②从形式上看,Na2CO3和Na2SO3相似,但是从上述实验中可以看到,二者的水溶液与氯化铁溶液反应的现象差别很大,其可能的原因除SO32-水解能力较CO32- 填“大”或“小”)外,还有                                    

答案

2Fe3++SO32-+H2O=2Fe2++SO42-+2H+⑵①BaCl2溶液、稀盐酸⑶①Fe3+与SO32-同时发生氧化还原反应和双水解反应②Fe(OH)3(胶体)+ 3SCN- = Fe(SCN)3 + 3OH-⑷①2Fe3+ + 3CO32- + 3H2O = 2Fe(OH)3+ 3CO2↑ ②小   SO32-有较强的还原性,而CO32没有还原性

阅读理解

In today’s world of mobile phones, most people have at least one time-telling tool with them. Since these small machines are so common, will people stop wearing the 500-year-old watches? According to some people, yes. A teenager says it’s unnecessary to wear a watch. Many young people agree-and use their mobile phones to tell time. Louis Galie, apresident, said that fewer young people wear watches today than five years ago.

However, watchmakers say that watches get popular again when people reach their 20s and 30s. By then, they want to spend money on a nice time-telling tool which doesn’t just keep a good time. For this reason, the watch industry has become an accessory business (配件业) in recent years.

Today’s ______ offer a lot of uses that meet the need of almost any personality (个性). They can be used as compasses (指南针), calendars, and even USB drivers…

People are always trying their best to creat new kinds of watches. A certain watchmaker business watches that don’t even look like watches. Their popular model uses different color lights to tell the time. Amother watchmaker business, make a “handless” watch, using a ring of circles to keep time. This watch makes people talk a lot about modern watches.

Whether a watch express fashion sense, creative ability of a love of sports, people want their time-telling tools to be beautiful, fashionable and practical. All in all, a watch has become more important than the time it tells.

小题1: Many young people agree that it’s unnecessary to __________________.

小题2:When do watches get popular again according to watchmakers?

______________________________________________________________

小题3: ___________________________________________________________

小题4: ___________________________________________________________

小题5:___________________________________________________________

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