问题 填空题

若从H2SO4、Na2CO3、Na2SO4、NaCl、NaNO3、Cu(NO32、HNO3七种溶液中取出其中的两种,进行混合及有关实验,所观察到的现象记录如下表.试根据各步实验及其现象先进行分步推断,再推断所取的两种溶液的可能组合.

步骤实验操作实验现象分步推断
(1)将取出的2种溶液进行混合混合溶液无色、澄清.

无其它明显现象

混合溶液中肯定不含Cu(NO32
(2)用pH试纸测定混合溶液的pH测定结果pH=2混合溶液中肯定不含______
(3)向混合溶液中滴入足量的Ba(NO32溶液有白色沉淀出现混合溶液中可能含有______
(4)向(3)中溶液过滤所得的滤液中滴加AgNO3溶液无明显现象混合溶液中肯定不含______
混合溶液的可能组合(写出溶质的化学式)①______和______ 或

②______和______(写出两种组合即可)

答案

(1)相互间能生成沉淀、气体的反应均不行,如H2SO4与Na2CO3或HNO3与Na2CO3它们反应会生成气体,故答案为:H2SO4与Na2CO3或HNO3与Na2CO3

(2)实验测定pH为2,故溶液显酸性,而题目中显酸性的物质有两种:H2SO4、HNO3,结合实验(1)的结论,不能存在碳酸钠.故答案为:溶液中含有H2SO4或HNO3中的至少一种,不含碳酸钠.

(3)能与硝酸钡反应生成沉淀的物质有:H2SO4、Na2SO4,故答案为:H2SO4和Na2SO4至少含有一种.

(4)加入硝酸银无现象说明溶液中没有与硝酸银反应的物质,题目中能与硝酸银反应的有氯化钠和碳酸钠,而碳酸钠在(2)中已经排除,故答案为:溶液中不含NaCl.

根据各处实验结论可得满足所有情况的组合只有四种,

故答案为:①H2SO4与Na2SO4

②H2SO4与NaNO3

③H2SO4与HNO3

④HNO3与Na2SO4

多选题
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