问题 填空题

下列分子结构:CO2、CH4、PCl5、Na2O2、MgF2,其中原子的最外层不能都满足8电子稳定结构的是             ;属于离子化合物,且离子个数之比是2:1或1:2的是             。

答案

PCl5、CH4、NaOH;  Na2O2、MgF2

题目分析:PCl5、CH4、NaOH中磷元素、氢元素中原子最外层电子数均不能满足8电子稳定结构; Na2O2中需注意两个氧原子是以共价键的形式结合的,因此其中只含有一个阴离子,故“属于离子化合物,且离子个数之比是2:1或1:2的是Na2O2、MgF2”。

点评:此题属于基础题,也是易错题。易错点在于对Na2O2结构的不理解,需注意Na2O2中两个氧原子是以共价键的形式形成一个阴离子。

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