问题 实验题

(15分)现用下图所示装置及所给药品探究工业制硫酸时二氧化硫的转化率。已知C中含硫酸nmol,设气体进入C和D时能分别完全吸收某一种气体,且忽略装置内空气中的CO2

请回答下列问题:

(1)检查完装置的气密性且加入药品后,开始进行时首先应进行的操作是

                                                                  

(2)通过观察中气泡的逸出速率可控制SO2和O2的流量和体积比,A装置还起的作用有                                                                   

(3)为了提高测定SO2转化率的准确度,下列操作或改进可行的是(填序号)     

①熄灭酒精灯后,停止通入SO2,继续通入O2一段时间

②熄灭酒精灯后,停止通入O2,继续通入SO2一段时间

③在C、D之间加装一个盛有浓硫酸的洗气瓶

(4)若气体经过充分,实验结束后,稀释装置C中的溶液,并向其中加入足量的BaCl2溶液,得到的沉淀质量为w g。若装置D增加的质量为a g,则二氧化硫的转化率是:

                                     (用含字母的代数式表示,结果可不化简)。

(5)若向接触室中通入2 molSO2(g)和1molO2(g),在一定温度下,反应达到平衡时测得接触室内的压强为起始时的0.75倍,则SO2的转化率为            ;相同条件下,当起始时同时通入a mol SO2、b mol O2、c mol SO3(g)时,达到平衡时与原平衡等效,且起始时维持化学反应向逆反应方向进行,则c的取值范围为                        

答案

(1)点燃B处的酒精灯,给催化剂加热。  (2分)

(2)干燥气体;使SO2和O2均匀混合。 (每答对一点得1分,共2分)

(3)①③   (选对一个得1分,有错不得分,2分)  

(4)  (答 也可给分)(4分)

(5)75% (2分),   1.5<c<2 (答出“≤”者皆不得分,带上单位扣1分,3分)。

单项选择题
阅读理解

     Driving a car is not just handling controls and judging speed and distance. It requires you to predict

what other road users will do and get ready to react to something unexpected. When alcohol is

consumed, it enters your bloodstream and acts as a depressant(抑制药), damaging eyesight, judgement

and coordination(协调), slowing down reaction time and greatly increasing the risk of accidents. Even

below the drink driving limit, driving will be affected.

      Alcohol may take a few minutes to be absorbed into the bloodstream and start action on the brain.

Absorption rate is increased when drinking on an empty stomach or when consuming drinks mixed with

fruit juice. To get rid of alcohol from the body is a very slow process and it is not possible to speed it up

with any measures like taking a shower or having a cup of tea or coffee.

     The present Road Traffic Ordinance states clearly that the limit of alcohol concentration is:

     ● 50 milligrams of alcohol per 100ml of blood; or

     ● 22 micrograms of alcohol per 100ml of breath; or

     ● 67 milligrams of alcohol per 100ml of urine(尿液).

     Drivers who cause traffic accidents, or who commit a moving traffic offence or are being suspected of

drink driving will be tested.

     Any driver found drinking beyond the limit will be charged. The driver declared guilty may be fined a

maximum of HK $25,000 and be sentenced to up to 3 years in prison and punished for 10

drivingoffence points; or temporarily banned from driving.

     The same punishment applies to failing to provide specimens(样本) for breath, blood or urine tests

without good excuse.

      Drink driving is a criminal offence. Be a responsible driver, think before you drink. For the safety of

yourself and other road users, never drive after consuming alcohol.

1. The first paragraph is mainly about ________.

A. the introduction of driving skills

B. the damage of drinking to your body

C. the effect of drinking on driving

D. the process of alcohol being absorbed

2. The underlined word "it" in the second paragraph refers to "________".

A. alcohol   

B. absorption

C. blood  

D. process

3. Which of the following is TRUE according to the passage?

A. Drinking below the drink driving limit has no effect on driving.

B. Alcohol is taken in more quickly when drunk with fruit juice.

C. Having a cup of tea helps to get rid of alcohol from the body.

D. 50 milligrams of alcohol per 100ml of breath is below the drink driving limit.

4. A driver suspected of drink driving________.

A. should provide specimens for testing

B. will be forbidden to drive for 3 years

C. will be punished for 10 drivingoffence points

D. should pay a maximum fine of HK$25,000