问题 问答题 简答题

抗坏血酸褐变的反应历程。

答案

参考答案:

抗坏血酸不仅具有酸性还具有还原性,因此,常作为天然抗氧化剂。抗坏血酸在对其它成分抗氧化的同时它自身也极易氧化,其氧化有两种途径:

(1)有氧时抗坏血酸被氧化形成脱氢抗坏血酸,再脱水形成DKG(2,3-二酮古洛糖酸)后,脱羧产生酮木糖,最终产生还原酮。还原酮极易参与美拉德反应德中间及最终阶段。此时抗坏血酸主要是受溶液氧及上部气体的影响,分解反应相当迅速。

(2)当食品中存在有比抗坏血酸氧化还原电位高的成分时,无氧时抗坏血酸因脱氢而被氧化,生成脱氢抗坏血酸或抗坏血酸酮式环状结构,在水参与下抗坏血酸酮式环状结构开环成2,3-二酮古洛糖酸;2,3-二酮古洛糖酸进一步脱羧、脱水生成呋喃醛或脱羧生成还原酮。呋喃醛、还原酮等都会参与美拉德反应,生成含氮的褐色聚合物或共聚物类。抗坏血酸在pH<5.0的酸性溶液中氧化生成脱氢抗坏血酸,速度缓慢,其反应是可逆的。

判断题
单项选择题

When Dr. John W.Gofman, professor of medical physics at the University of California and a leading nuclear critic, speaks of "ecocide" in his adversary view of nuclear technology, he means the following: A large nuclear plant like that in Kalkar, the Netherlands, would produce about 200 pounds of plutonium each year. One pound, released into the atmosphere, could cause 9 billion cases of lung cancer. This waste product must be stored for 500,000 years before it is of no further danger to man. In the anticipated reactor economy, it is estimated that there will be 10,000 tons of this material in Western Europe, of which one table-spoonful of plutonium-239 represents the official maximum permissible body burden for 200,000 people. Rather than being biodegradable, plutonium destroys biological properties.

In 1972 the U.S. Occupational Safety and Health Administration ruled that the asbestos level in the work place should be lowered to 2 fibers per cubic centimeter of air, but the effective date of the ruling has been delayed until now. The International Federation of Chemical and General Workers’ Unions report that the 2-fiber standard was based primarily on one study of 290 men at a British asbestos factory. But when the workers at the British factory had been reexamined by another physician, 40--70 percent had X-ray evidence of lung abnormalities. According to present medical information at the factory in question, out of a total of 29 deaths thus far, seven were caused by lung cancer. An average European or American worker comes into contact with six million fibers a day. "We are now, in fact, finding cancer deaths within the family of the asbestos worker," states Dr. Irving Selikoff, of the Mount Sinai Medical School in New York.

It is now also clear that vinyl chloride, a gas from which the most widely used plastics are made, causes a fatal cancer of the blood-vessel cells of the liver. However, the history of the research on vinyl chloride is, in some ways, more disturbing than the "Watergate cover-up." "There has been evidence of potentially serious disease among polyvinyl chloride workers for 25 years that has been incompletely appreciated and inadequately approached by medical scientists and by regulatory authorities," summed up Dr. Selikoff in the New Scientist. At least 17 workers have been killed by vinyl chloride because research over the past 25 years was not followed up. And for over 10 years, workers have been exposed to concentrations of vinyl chloride 10 times the "safe limit" imposed by Dow Chemical Company. (422 words)

Notes: plutonium 钚。asbestos 石棉。polyvinyl chloride 聚氯乙烯。

It can be inferred from the text that the author believes that()

A. nationwide application of anti-pollution devices can finally prevent cancer

B. tough legislation is needed to set lower limits of worker exposure to harmful chemicals

C. more research is required into the causes of cancer before further progress can be made

D. industrialization must be slowed down to prevent further spread of cancer-causing agents