某K2CO3样品中含有Na2CO3、KNO3、Ca（NO3）2三种杂质中的一种或两种．现将13.8g样品加入足量水，样品全部溶解，再加入过量的CaCl2溶液，得到9g沉淀．对样品所含杂质的判断不正确的是（ ）
A．可能只有Na2CO3
B．可能只有KNO3
C．肯定有KNO3，可能还含有Na2CO3
D．肯定没有Ca（NO3）2
样品加入水中，全部溶解，说明一定无硝酸钙（因为硝酸钙能够和碳酸钾反应生成沉淀），假设13.8g纯碳酸钾产生碳酸钙的质量为x，则有
K2CO3+CaCl2═CaCO3↓+2KCl
138 100
13.8g x
=138 13.8g 100 x
x=10g
假设13.8g纯碳酸钠产生碳酸钙的质量为y，则有
Na2CO3+CaCl2═CaCO3↓+2NaCl
106 100
13.8g y
=106 13.8g 100 y
y≈13g
若含有碳酸钠则得到沉淀的质量应该大于10g小于13g，而实际只得到9g，故不可能只含有碳酸钠，一定含有硝酸钾，观察选项，故选A．
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