问题 实验题

某科研小组用MnO2和浓盐酸制备Cl2时,利用刚吸收过少量SO2的NaOH溶液对其尾气进行吸收处理。

(1)请完成SO2与过量NaOH溶液反应的化学方程式: ________________.

(2)反应Cl2+Na2SO3+2 NaOH===2NaCl+Na2SO4+H2O中的还原剂为_________.

(3)请完成MnO2和浓盐酸制备Cl2的离子方程式: _______  _________.

(4)如果14.2g氯气与足量的氢气反应,然后生成的气体用500mL某浓度的NaOH溶液恰好反应,则此NaOH的浓度为         (请写出计算过程)

(5)吸收尾气一段时间后,吸收液(强碱性)中肯定存在Cl、OH和SO.请设计实验,探究该吸收液中可能存在的其他阴离子(不考虑空气的CO2的影响).

①提出合理假设 .

假设1:只存在SO32-;假设2:既不存在SO32-也不存在ClO;假设3:SO32-、ClO都存在。

设计实验方案,进行实验。请在答题卡上写出与实验步骤相应的预期现象和结论。限选实验试剂:3moLL-1H2SO4、1moLL-1NaOH、0.01molL-1KMnO4、淀粉-KI溶液、紫色石蕊试液.

实验步骤预期现象和结论
步骤1:取少量吸收液于试管中,滴加3 moLL-1 H2SO4至溶液呈酸性,然后将所得溶液分置于A、B试管中. 
步骤2:在A试管中滴加紫色石蕊试液 
步骤3:在B试管中滴加0.01molL-1KMnO4 
 

答案

(1)SO2   +   2 NaOH="== " Na2SO3  +   H2O                 

(2)Na2SO3

(3)MnO+ 2Cl  +4H+ ="==  " Cl2    +  Mn2+  +  2H2O

(4)解:n(Cl2 )=14.2g/71g·mol=0.2(mol)

Cl2  +    H2   ="==  " 2HCl

0.2mol                0.4mol        (2分)

HCl   +   NaOH ="== " NaCl +   H2O

0.4mol     0.4mol

C( NaOH)=" 0.4mol/0.5L=0.8mol/L       " (2分)

(5)②

阅读理解

One bag, that’s it.

The importance of packing light cannot be overemphasized(过度强调). Limit yourself to 20 pounds in a carry-on bag. A 9’× 22’ ×14’ bag fits under most airplane seats. And after you enjoy that sweet mobility and freedom, you’ll never go any other way.

You’ll walk with your luggage(行李) more than you think you will. Before leaving home, give yourself a test. Pack up completely, and practice being a tourist for an hour. Fully loaded, you should enjoy window-shopping. If you can’t, go home and thin things out.

Packing light isn’t just about the trip over and back—it’s about your traveling lifestyle. Too much luggage marks you as a typical tourist. It slams the back door shut. Changing locations becomes an important operation. With only one bag, you’re mobile and in control. Take this piece of advice seriously. Pack light, and pack smart. These days, you can’t bring anything possibly dangerous—such as knives, lighters or large amounts of liquid (液体)—in your bag.

What to bring?

How do you fit a whole trip’s worth of luggage into a small backpack or suitcase(衣箱)? The answer is simple: bring very little.

Bring out everything you think you might need on the floor. Pick up one item(件) at a time and check it. Ask yourself—not “Will I use it?”, but—“Will I use it enough to feel good about carrying it all the way? The world is getting really small—you can buy Colgate toothpaste, Nivea cream and Gillette razors in almost every country.

Think about what you can do without—not what will be convenient on your trip. When in doubt, leave it out.

小题1:What do the last two paragraphs mainly talk about?

A.Packing light is a kind of travelling lifestyle.

B.Packing light can give you mobility and freedom.

C.How to find out what to take and what not to take on a trip.

D.How to find out if your luggage is too heavy.小题2:You are allowed to take _______with you when you travel according to the passage.

A.Colgate toothpaste

B.Lighters

C.Knives

D.a great deal of liquid小题3:The underlined part “thin things out” possibly means________.

A.make things thin to bring

B.make your luggage lighter

C.take out dangerous things

D.throw useless things away小题4:The author seems to believe that _________.

A.people had better bring nothing when they travel

B.people can use Nivea cream only in their home town

C.the importance of packing light is overemphasized now

D.you will be easily seen as a tourist with a lot of luggage小题5:What is the best title for the passage?

A.Dying for a trip

B.Things to take on a trip

C.Pack light and pack right

D.Travelling: a typical way of life

多项选择题 案例分析题