问题 选择题

将50mL某未知浓度的AlCl3溶液分别加到60mL1mol/LNaOH溶液或是60mL3mol/LNaOH溶液中,均能得到1.56gAl(OH)3沉淀,则AlCl3溶液的浓度可能是

A.0.4mol/L

B.0.5mol/L

C.0.6mol/L

D.1mol/L

答案

答案:D

解:1.56gAl(OH)3沉淀,其物质的量为1.56g/78g/mol=0.02mol,

①由加到60mL1mol/LNaOH溶液中只发生Al3++3OH-═Al(OH)3↓,

碱完全反应,则AlCl3溶液的浓度应≥0.02mol/0.05L=0.4mol/L,

②由加到60mL3mol/LNaOH溶液中发生Al3++3OH-═Al(OH)3↓、Al(OH)3+OH-═AlO2-+2H2O,

设此AlCl3溶液的溶质的物质的量为x,则

Al3++3OH-═Al(OH)3

x     3x     x

Al(OH)3+OH-═AlO2-+2H2O

x-0.02   x-0.02

根据消耗的碱的物质的量可知,3x+(x-0.02)=0.06×3,

解得x=0.05mol,

此AlCl3溶液的浓度为0.05mol/0.05L=1mol/L,

由①②可知,此AlCl3溶液的浓度为1mol/L,故选D.

点评:本题考查铝离子与碱的反应,明确碱的物质的量对发生的化学反应的影响、氢氧化铝的能溶于强碱时解答本题的关键,难度不大.

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