问题 填空题

美日三名化学家[理查德·赫克(Richard Heck,美)、根岸荣—(Ei – ich Negishi,日)、铃木章(Akira Suzuki,日)利用钯(Pd)作催化剂,将有机化合物进行“裁剪”、“缝合”,创造出具有特殊功能的新物质而荣获2010年诺贝尔化学奖。赫克反应(Heck反应)的通式可表示为(R – X中的R通常是不饱和烃基或苯环;R′CH=CH通常是丙烯酸酯或丙烯腈等):

现有A、B、C、D等有机化合物有如下转化关系:

请回答下列问题:

(1)反应I的化学方程式为                                      

(2)已知腈基(—C≡N)也具有不饱和性(可催化加氢),写出CH2=CH—CN完全催化加氢的化学方程式:                                        

(3)丙烯腈(CH2=CH—CN)可发生加聚反应生成一种高聚物,此高聚物的结构简式为

                             

(4)写出B转化为C的化学方程式:                          

(5)D的结构简式为(必须表示出分子的空间构型)                    

(6)D具有化学性质有(填编号)            

A.加热能与氢氧化钠溶液反应

B.能使溴的四氯化碳溶液褪色

C.能发生缩聚反应和加聚反应

D.能使酸性高锰酸钾溶液褪色

(7)已知:醛基直接与苯环连接的醛如不能被新制的氢氧化铜氧化。写出同时符合下列条件的D的同分异构体的结构简式:              

①波谱分析显示分子中没有甲基;

②1,3,5—三取代苯;

③具有酸性,既能与Fe3+作用显色,又能使溴水褪色,易被新制的氢氧化铜氧化

答案

句型转换

阅读短文,完成下列各题。

Once there was an old farmer, with a horse which was almost as old as himself. He set out one morning with his son to sell the horse before it died. Father and son walked, because the farmer did not want the horse to be too tired.

  Two men on the road said, "Why are you walking, farmer? You have a horse, It's a long way to market. "The farmer thought that it was true, so he rode on the horse, while his son walked.

  Then they met two old women, "What are you doing up there, farmer? Can't you see how tired the boy is?" So the farmer got down, and his son rode instead.

  Next, an old men stopped them and said, "Why are you walking, farmer?  It's too hot for an old man like you to walk today," So the farmer got up behind his son, and they rode on.

Some time later, a young woman passed them, "Why aren't you walking?" she said, "It isn't far to the market. Let your poor horse have a rest." So the farmer, and his son, got down once again.

It is a fact that you cannot please all the people all the time.

简略回答问题。

小题1:Why did the father and son walk first? _________________________.

小题2:What does the story tell us?  _____________________

小题3:He set out one morning with his son.  (划线部分提问)

______  ______  he set out with his son?

小题4:You have a horse (否定句)

You _______   _________  a horse.

小题5:She said, "It isn't far to the market.”(改为宾语从句)

She said _______   _______ far to the market.

填空题