问题 填空题

已知A为中学化学中的一种盐,B、C为日常生活中常见的金属.通常条件下D、G为无色无味气体.已知用惰性电极电解A溶液一段时间后,产物只有C、D和E的稀溶液.各物质之间的转化关系如图(部分反应产物已略去).

请回答下列问题:

(1)A的化学式为______.

(2)A溶液与Na2O2反应的总化学方程式为______.

(3)E的稀溶液与F溶液反应的离子方程式为______.

(4)电解100mL盐A的溶液一段时间后,断开电路,取出电极,测得所得到的气体D在标准状况下的体积为5.6mL,则电解后溶液的pH为______.(假设溶液体积不变)

(5)若向100mL盐A的溶液中加入10g金属单质B的粉末,充分搅拌后,过滤,烘干得10.16g固体C.则滤液中溶质的物质的量浓度为______.(假设溶液体积不变)

答案

(1)电解A溶液时产生金属单质C和另外一种气体D,应为电解含氧酸盐溶液,在阴极上析出不活泼金属,则C应为铜,D为氧气,E溶液能与C金属发生氧化还原反应,且E溶液与F溶液也能反应生成无色无味气体G,说明E溶液具有强氧化性,应为硝酸,故A为硝酸,C为铜,D为氧气,G为NO,F与硝酸反应生成NO,说明且含有金属B元素,说明F溶液具有还原性,应为Fe(NO32溶液,B为Fe,H为Fe(NO33,故答案为:Cu(NO32

(2)Na2O2与水加入到Cu(NO32溶液中反应生成NaOH和氧气,NaOH和Cu(NO32反应生成蓝色沉淀2Cu(OH)2,故答案为:2Na2O2+2Cu(NO32+2H2O=2Cu(OH)2↓+4NaNO3+O2↑;

(3)硝酸具有强氧化性,Fe2+具有还原性,二者发生氧化还原反应,故答案为:3Fe2++NO3-+4H+═3Fe3++NO↑+2H2O;

(4)根据电解硝酸铜的电极方程式:

2Cu(NO32+2H2O

 电解 
.
 
2Cu+O2↑+4HNO3

                      22.4L   4mol

                     5.6×10-3L  n

则n=

4×mol×5.6×10-3
22.4L L
=1×10-3mol

所以c(H+)=

10-3mol
0.1L
=0.01mol,故PH=2,故答案为:2;

(5)向盐A溶液中加入金属单质B,反应的化学方程式为:Fe+Cu(NO32═Fe(NO32+Cu,根据差量法计算:

Fe+Cu(NO32═Fe(NO32+Cu△m

    1mol                    8g

    n                      10.16g-10g=0.16g

n=

0.16
8
=0.02mol,所以溶液的浓度为:
0.02mol
0.1L
=0.2mol/L,故答案为:0.2 mol/L.

完形填空
完形填空
     Sharon is a    1    girl. Today Mr and Mrs Black are    2    her to the amusement park(游乐场). The amusement park
is    3    far from    4    home. So they are taking the  subway to go there. There are only a few people on the train. They
are all sitting    5    their seats. Sharon is happy. She is looking    6    from the window.  "Come here and    7   , "Mr Black
says.
"I want this train can go    8    faster, then I can play in the park. "    It takes about forty minutes to arrive at the park.
They    9    the tickets and go in. At noon, the Blacks are sitting    10    the table in the park. They're having lunch happily.
( )1. A. ten year old
( )2. A. taking      
( )3. A. quite      
( )4. A. their      
( )5. A. at          
( )6. A. out        
( )7. A. stands up  
( )8. A. much        
( )9. A. find        
( )10. A. in        
B. ten-year-old
B. carrying    
B. a lot      
B. they        
B. for        
B. in          
B. sit down    
B. more        
B. sell        
B. at          
C. ten-years old
C. having      
C. much        
C. them        
C. on          
C. for          
C. to sit down  
C. most        
C. lose        
C. on          
D. ten-years-old
D. bringing    
D. a few        
D. her          
D. in          
D. outside      
D. standing up  
D. the most    
D. buy          
D. under        
填空题