问题 填空题

(13分)A、B、C、D、E、F是原子序数依次增大的短周期主族元素,A的最外层电子数是次外层电子数2倍,B是短周期中金属性最强的元素,C是同周期中阳离子半径最小的元素,D元素的最高价氧化物对应水化物与B元素的最高价氧化物对应水化物反应的产物M是制备木材防火剂的原料,E的最外层电子数与内层电子数之比为3﹕5。

请回答:

(1)D的元素符号为           

(2)F在元素周期表中的位置           

(3)用电子式表示由元素B和F组成的化合物的形成过程:                          。(4)B单质与氧气反应的产物与C的单质同时放入水中,产生两种无色气体,有关的化学方程式为                                        

(5)工业上将干燥的F单质通入熔融的E单质中可制得化合物E2F2,该物质可与水反应生成一种能使品红溶液褪色的气体,0.2mol该物质参加反应时转移0.3mol电子,其中只有一种元素化合价发生改变,该反应的化学方程式为

                                              

(6)某混合物的稀溶液中,只可能含有B、C、F构成的简单离子或A、E的最高价氧化物对应水化物所电离出来的阴离子。现分别取一定体积的该溶液进行实验。两次每次取200.00mL进行实验。

实验1:取2mL溶液,向其中加入AgNO3溶液有沉淀产生;

实验2:取200mL溶液,向其中加入足量BaCl2溶液后,得干燥沉淀12.54g,沉淀经足量盐酸洗涤、干燥后,剩余4.66g。

请回答:

①根据以上实验,不能判断是否存在的离子有             

② B的简单离子是否存在?     ;若存在,浓度至少为     mol/L(若不存在,则不必回答第二问)。

答案

(13分)

(1)Si

(2)第3周期,VIIA(2分)

(3)

(4)2Na2O2 + 2H2O ="=" 4NaOH + O2↑  2Al+ 2NaOH + 2H2O ="==" 2NaAlO2 +3H2

(5)2S2Cl2 + 2H2O ="=" 3S + SO2↑+ 4HCl (2分)

(6)①Cl-  HCO3-  (各1分,共2分)

②存在,0.6 (2分)

单项选择题
单项选择题

A total of 4.6 million digital televisions have been sold, and the sales of HDTV sets have quadrupled since last year. Consumers have bought HDTVs to play their DVDs and to have clearer pictures and wide screens. Only a small percentage of the people who have purchased HDTVs, however, have actually hooked their TVs up to receive high-definition television digital signals. Perhaps television viewers are having trouble keeping up with the changes in technology. Even the manufacturers of HDTVs, like Mitsubishi, Thomson Multimedia, Sony, and Samsung seem to have a tough time learning how to make their sets work with the various digital TV formats because little standardization has been required or implemented in the industry.

Some of the HDTVs weigh over 200 lbs., and a variety of retailers offer a delivery service to the buyer’s home to help install the heavy sets. This is known as a white-glove service and usually comes with an extra fee. After HDTV purchasers get their sets home and hook them up, they will still need to work to get the digital signals to their systems. Most of the industry’s cable providers do not yet offer high~definition programing, and only about 15% of commercial television stations have switched over to even the lowest improved digital pictures. Worse yet, viewers may need to install antenna before they can even get the digital signals to their new HDTV sets. Another frustration for home-theater seekers is that the current HDTV sets allow owners only to watch high-definition programs, not to record them.

A majority of HDTV consumers could not enjoy high-quality digital pictures because ().

A. they did not tune in to the right channel

B. they did not install the system

C. the market retailers created the confusion on purpose

D. the manufacturers did not have a uniform standard for their sets