问题 问答题

海水是盐的丰富宝藏,海水的咸、涩味感,是由于海水中除含有食盐以外,还含有多中盐类物质.已知海水中含有丰富的Na+、K+、Ca2+、Mg2+、Cl-、SO42-、等离子,通过晾晒海水,可以蒸发除去其水分,得到含有较多杂质的氯化钠晶体--粗盐.

你觉得粗盐晶体中的杂质是指什么物质,请你写出它们的化学式:______.

如果请你检测粗盐中是否含有SO42-,你的做法是:______.

答案

(1)可以将四种阳离子和两种阴离子两两组合形成物质,列如下:

  Na+ K+ Ca2+ Mg2+Cl-  SO42-
 Na+ ______ ______ ____ ______ NaCl Na2SO4
 K+ _____ _______ ______ ______ KCl K2SO4
 Ca2+ _________ ______ ______ _____ CaCl2 CaSO4
 Mg2+ ____ ______ ______ _____ MgCl2 MgCl2
Cl-  

 NaCl

 KCl CaCl2 MgCl2 ______ ______
 SO42-Na2SO4  K2SO4CaSO4 MgCl2 _______ _____
根据上表可知,粗盐晶体中的杂质是:Na2SO4、KCl、K2SO4、CaCl2、MgCl2、MgSO4(硫酸钙微溶于水,所以不能大量存在于溶液中).

(2)要检验硫酸根应该用含钡离子的化合物与硫酸根形成硫酸钡沉淀,与钡离子形成物质的阴离子又不能形成沉淀,加入的硝酸是为了排除碳酸根离子的干扰,故答案为:取少量粗盐溶于蒸馏水,再滴入2~3滴Ba(NO32溶液,如有白色沉淀,再加几滴稀硝酸,若沉淀不溶解,就说明精盐中含有SO42-离子.

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     Many a young person tells me he wants to be a writer. I always   1   such people, but I also explain that
there's a big   2   between "being a writer" and"writing".
     In most cases these individuals are dreaming of wealth and fame,   3   the long hours spent alone   4   .
"You've got to want to write," I say to them,"not want to be a writer."
     The   5   is that writing is a lonely, private and poor-paying affair. For every writer kissed by   6   there are
thousands more whose longing is   7   rewarded. When I   8   a 20-year career in the U.S. Coast Guard to
become a freehand writer, I had no prospects (前景) at all. What I   9   was a friend who found me a room in
a New York apartment building. It didn't   10   matter that it was cold and had no bathroom. I immediately
bought a (an)  11  manual typewriter and  12  a genuine writer.
     After a year or so,   13   , I still hadn't gotten a break and began to   14   myself. It was so hard to sell a
story that I   15   made enough to eat. But I knew I   16   write.
      I had dreamed about it   17   . I wasn't going to be one of those people who die  18       
     "What if?" I would keep putting my dream to the  19  even though it meant living with uncertainty and fear
of failure. This is the Shadow Land of  20 , and anyone with a dream must learn to live there.
( )1. A. advise       
( )2. A. step         
( )3. A. and         
( )4. A. in the room 
( )5. A. reality     
( )6. A. writing     
( )7. A. never       
( )8. A. began       
( )9. A. had had     
( )10. A. ever       
( )11. A. used       
( )12. A. felt like   
( )13. A. consequently
( )14. A. scold       
( )15. A. almost     
( )16. A. planned to 
( )17. A. for years   
( )18. A. regretting 
( )19. A. point       
( )20. A. time       
 B. encourage   
 B. advance     
 B. but         
 B. typewriting 
 B. idea       
 B. readers     
 B. always     
 B. found       
 B. have had   
 B. just       
 B. new         
 B. acted as   
 B. therefore   
 B. doubt       
 B. partly     
 B. ought to   
 B. long ago   
 B. wondering   
 B. best       
 B. death       
C. tell       
C. gap        
C. not        
C. with a novel 
C. news      
C. fortune     
C. sometimes 
C. left         
C. am having 
C. even      
C. useful       
C. typed like 
C. unluckily  
C. beat         
C. poorly     
C. was able to
C. since then 
C. dreaming     
C. test      
C. hope        
D. warn        
D. difference  
D. for         
D. for a desk  
D. reason      
D. others      
D. only        
D. put         
D. did have    
D. greatly     
D. old         
D. performed as
D. however     
D. hate        
D. barely      
D. wanted to   
D. once again  
D. depressing  
D. most        
D. life        
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